tert-Butyl-[(3Z,6Z)-1-(3-dimethoxymethyl-phenyl)-nona-3,6-dienyloxy]-diphenyl-silane

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Chemical Name:tert-Butyl-[(3Z,6Z)-1-(3-dimethoxymethyl-phenyl)-nona-3,6-dienyloxy]-diphenyl-silane
CAS No.:467217-02-3
Molecular Formula:C₃₄H₄₄O₃Si
Molecular Weight:528.807
Hs Code.:

Synonyms:tert-Butyl-[(3Z,6Z)-1-(3-dimethoxymethyl-phenyl)-nona-3,6-dienyloxy]-diphenyl-silane

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Chemical Property of tert-Butyl-[(3Z,6Z)-1-(3-dimethoxymethyl-phenyl)-nona-3,6-dienyloxy]-diphenyl-silane

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Technology Process of tert-Butyl-[(3Z,6Z)-1-(3-dimethoxymethyl-phenyl)-nona-3,6-dienyloxy]-diphenyl-silane

There total 7 articles about tert-Butyl-[(3Z,6Z)-1-(3-dimethoxymethyl-phenyl)-nona-3,6-dienyloxy]-diphenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 21676-06-2
(Z)-hex-3-en-1-yltriphenylphosphonium iodide

: 3-(tert-butyl-diphenyl-silanyloxy)-3-(3-dimethoxymethyl-phenyl)-propionaldehyde

: 467217-02-3
tert-Butyl-[(3Z,6Z)-1-(3-dimethoxymethyl-phenyl)-nona-3,6-dienyloxy]-diphenyl-silane

Guidance literature:: With n-butyllithium; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; at -80 ℃; for 4h;
DOI:10.1016/S0040-4039(02)01056-0

Reference yield:

: 626-19-7
Isophthalaldehyde

: 467217-02-3
tert-Butyl-[(3Z,6Z)-1-(3-dimethoxymethyl-phenyl)-nona-3,6-dienyloxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 7 steps

1: 90 percent / NH₄NO₃ / methanol / 2 h / Heating

2: 88 percent / SiO₂; aq. H₂SO₄ / CH₂Cl₂ / 0.75 h / 20 °C

3: 79 percent / LDA / tetrahydrofuran / 0.5 h / -80 °C

4: 91 percent / imidazole / dimethylformamide / 24 h / 20 °C

5: 50 percent / DIBAL-H / diethyl ether / 1.5 h / -60 °C

6: 78 percent / n-BuLi / hexamethylphosphoric acid triamide; tetrahydrofuran / 4 h / -80 °C

With 1H-imidazole; ammonium nitrate; n-butyllithium; sulfuric acid; silica gel; diisobutylaluminium hydride; lithium diisopropyl amide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; dichloromethane; N,N-dimethyl-formamide; 6: Swern oxidation / 7: Wittig reaction;
DOI:10.1016/S0040-4039(02)01056-0

Reference yield:

: 37832-33-0
isophthalaldehyde bis-dimethylacetal

: 467217-02-3
tert-Butyl-[(3Z,6Z)-1-(3-dimethoxymethyl-phenyl)-nona-3,6-dienyloxy]-diphenyl-silane

Guidance literature:: Multi-step reaction with 6 steps

1: 88 percent / SiO₂; aq. H₂SO₄ / CH₂Cl₂ / 0.75 h / 20 °C

2: 79 percent / LDA / tetrahydrofuran / 0.5 h / -80 °C

3: 91 percent / imidazole / dimethylformamide / 24 h / 20 °C

4: 50 percent / DIBAL-H / diethyl ether / 1.5 h / -60 °C

5: 78 percent / n-BuLi / hexamethylphosphoric acid triamide; tetrahydrofuran / 4 h / -80 °C

With 1H-imidazole; n-butyllithium; sulfuric acid; silica gel; diisobutylaluminium hydride; lithium diisopropyl amide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; dichloromethane; N,N-dimethyl-formamide; 5: Swern oxidation / 6: Wittig reaction;
DOI:10.1016/S0040-4039(02)01056-0