Z-2--1-tert-butyldimethylsilyloxy ethyl propenoate

Base Information

Chemical Name:Z-2--1-tert-butyldimethylsilyloxy ethyl propenoate
CAS No.:232266-97-6
Molecular Formula:C₁₇H₂₆O₃Si
Molecular Weight:306.477
Hs Code.:

Z-2-<phenyl>-1-tert-butyldimethylsilyloxy ethyl propenoate

Synonyms:Z-2--1-tert-butyldimethylsilyloxy ethyl propenoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Z-2--1-tert-butyldimethylsilyloxy ethyl propenoate

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Technology Process of Z-2--1-tert-butyldimethylsilyloxy ethyl propenoate

There total 2 articles about Z-2--1-tert-butyldimethylsilyloxy ethyl propenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 100-52-7
benzaldehyde

: 2-diphenylphosphine oxide-2-tert-butyldimethylsilyloxy ethyl acetate

: 232266-97-6
Z-2--1-tert-butyldimethylsilyloxy ethyl propenoate

: 232266-98-7
E-2--1-tert-butyldimethylsilyloxy ethyl propenoate

Guidance literature:: With lithium hexamethyldisilazane; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; for 1h; Ambient temperature;
DOI:10.1016/S0040-4020(99)00317-8

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 232266-97-6
Z-2--1-tert-butyldimethylsilyloxy ethyl propenoate

: 232266-98-7
E-2--1-tert-butyldimethylsilyloxy ethyl propenoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: triethylamine / toluene / 0.25 h / 0 °C / Inert atmosphere

1.2: 3 h / 0 - 20 °C / Inert atmosphere

1.3: 20 °C / Inert atmosphere

2.1: lithium tert-butoxide / tetrahydrofuran / 0.25 h / Inert atmosphere

2.2: 1 h / 50 °C / Inert atmosphere

With triethylamine; lithium tert-butoxide; In tetrahydrofuran; toluene;
DOI:10.1021/acs.joc.9b02015