4(R)-<(tert-butyldiphenylsilyl)oxy>dodeca-2(E),6(Z)-dienal

Base Information Edit

Chemical Name:4(R)-<(tert-butyldiphenylsilyl)oxy>dodeca-2(E),6(Z)-dienal
CAS No.:100311-75-9
Molecular Formula:C₂₈H₃₈O₂Si
Molecular Weight:434.694
Hs Code.:
Mol file:100311-75-9.mol

Synonyms:4(R)-<(tert-butyldiphenylsilyl)oxy>dodeca-2(E),6(Z)-dienal

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Chemical Property of 4(R)-<(tert-butyldiphenylsilyl)oxy>dodeca-2(E),6(Z)-dienal Edit

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Technology Process of 4(R)-<(tert-butyldiphenylsilyl)oxy>dodeca-2(E),6(Z)-dienal

There total 19 articles about 4(R)-<(tert-butyldiphenylsilyl)oxy>dodeca-2(E),6(Z)-dienal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 100428-42-0
2(R)-<(tert-butyldiphenylsilyl)oxy>dec-4(Z)-enal

: 2136-75-6
(triphenylphosphoranylidene)acetaldehyde

: 100311-75-9
4(R)-<(tert-butyldiphenylsilyl)oxy>dodeca-2(E),6(Z)-dienal

Guidance literature:: In benzene; for 16h; Heating;
DOI:10.1021/jo00358a016

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 100311-75-9
4(R)-<(tert-butyldiphenylsilyl)oxy>dodeca-2(E),6(Z)-dienal

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / imidazole / tetrahydrofuran / 8 h / 25 °C

2: 78 percent / trimethylsilyl iodide, propene / CHCl₃ / 0.5 h / 25 °C

3: 90 percent / benzene / 16 h / Heating

With 1H-imidazole; propene; trimethylsilyl iodide; In tetrahydrofuran; chloroform; benzene;
DOI:10.1021/jo00358a016

Reference yield:

: 119414-22-1
9(R),12(R)-bis<(tert-butyldiphenylsilyl)oxy>-10(S),11(S)-O-(1-methylethylidene)-6,14-icosadiyne-10,11-diol

: 100311-75-9
4(R)-<(tert-butyldiphenylsilyl)oxy>dodeca-2(E),6(Z)-dienal

Guidance literature:: Multi-step reaction with 4 steps

1: 100 percent / hydrogen / Lindlar catalyst / benzene / Ambient temperature

2: 70 percent / (CH₂SH)2, TsOH / CHCl₃ / 3 h / Heating

3: 55 percent / lead tetraacetate / benzene / 1 h / Ambient temperature

4: 61 percent / benzene / 6 h / Heating

With lead(IV) acetate; hydrogen; toluene-4-sulfonic acid; ethane-1,2-dithiol; Lindlar's catalyst; In chloroform; benzene;
DOI:10.1021/jo00271a032