119414-22-1

Basic information

• Product Name: 9(R),12(R)-bis<(tert-butyldiphenylsilyl)oxy>-10(S),11(S)-O-(1-methylethylidene)-6,14-icosadiyne-10,11-diol
• Synonyms: 9(R),12(R)-bis<(tert-butyldiphenylsilyl)oxy>-10(S),11(S)-O-(1-methylethylidene)-6,14-icosadiyne-10,11-diol
• CAS NO: 119414-22-1
• Molecular Weight: 855.361
• Mol File: 119414-22-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 9(R),12(R)-bis<(tert-butyldiphenylsilyl)oxy>-10(S),11(S)-O-(1-methylethylidene)-6,14-icosadiyne-10,11-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 9(R),12(R)-bis<(tert-butyldiphenylsilyl)oxy>-10(S),11(S)-O-(1-methylethylidene)-6,14-icosadiyne-10,11-diol(119414-22-1)
• EPA Substance Registry System: 9(R),12(R)-bis<(tert-butyldiphenylsilyl)oxy>-10(S),11(S)-O-(1-methylethylidene)-6,14-icosadiyne-10,11-diol(119414-22-1)

Safety Data

• Hazardous Substances Data: 119414-22-1(Hazardous Substances Data)

Upstream product

• 628-71-7 1-Heptyne 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 63700-05-0 1,2;5,6-dianhydro-3,4-O-isopropylidene-D-mannitol 
• 42017-07-2 1-heptynyllithium 
• 1053634-06-2 (R)-1-[(4R,5R)-5-((R)-1-Hydroxy-non-3-ynyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-non-3-yn-1-ol 

Downstream Products

• 70578-51-7 6-trans-Leukotriene B₄ 
• 178060-97-4 (2E,4E)-(R)-6-(tert-Butyl-diphenyl-silanyloxy)-tetradeca-2,4-dien-8-ynal 
• 178060-99-6 [(R)-1-((1E,3E)-5-Bromo-penta-1,3-dienyl)-non-3-ynyloxy]-tert-butyl-diphenyl-silane 
• 178060-98-5 (2E,4E)-(R)-6-(tert-Butyl-diphenyl-silanyloxy)-tetradeca-2,4-dien-8-yn-1-ol 
• 116012-52-3 (2E,4R)-4-<(tert-butyldiphenylsilyl)oxy>-2-dodecen-6-ynal 
• 90108-26-2 (2R)-2-<(tert-butyldiphenylsilyl)oxy>-4-decynal 
• 119413-60-4 ethyl 6(S)-(benzoyloxy)-13(R)-<(tert-butyldiphenylsilyl)oxy>-7(E),9(E),11(E),15(Z)-henicosatetraenoate 
• 119392-39-1 ethyl 6(S)-(benzoyloxy)-13(R)-<(tert-butyldiphenylsilyl)oxy>-7(Z),9(E),11(E),15(Z)-henicosatetraenoate 
• 82493-60-5 (5S,12R,6Z,8E,10E,14Z)-ethyl 5-benzoyloxy-12-hydroxyicosatetra-6,8,10,14-enoate 
• 82493-61-6 ethyl 5(S)-(benzoyloxy)-12(R)-<(tert-butyldiphenylsilyl)oxy>-6(E),8(E),10(E),14(Z)-icosatetraenoate 
• 82493-59-2 ethyl 5(S)-(benzoyloxy)-12(R)-<(tert-butyldiphenylsilyl)oxy>-6(Z),8(E),10(E),14(Z)-icosatetraenoate 
• 82498-75-7 ethyl 6(R)-<(tert-butyldiphenylsilyl)oxy>-2(E).4(E),8(Z)-tetradecatrienoate 
• 100311-75-9 4(R)-<(tert-butyldiphenylsilyl)oxy>dodeca-2(E),6(Z)-dienal 
• 100428-42-0 2(R)-<(tert-butyldiphenylsilyl)oxy>dec-4(Z)-enal 

Relevant articles and documents

Total Synthesis of Leukotriene B44> and Homo-LTB4 from D-Mannitol

A convergent total synthesis of leukotriene B4 and its homo analogue has been carried out via enantiomerically pure α-hydroxy aldehydes, chiral key intermediates obtained from D-mannitol and connected at a four carbon atom interval by Wittig re