(η-cyclo-octa-1,5-diene)tris(N,N-dimethylhydrazine)hydridoruthenium(II) tetraphenylborate

Base Information

• Chemical Name: (η-cyclo-octa-1,5-diene)tris(N,N-dimethylhydrazine)hydridoruthenium(II) tetraphenylborate
• CAS No.: 65390-74-1
• Molecular Formula: C₁₄H₃₇N₆Ru*C₂₄H₂₀B
• Molecular Weight: 709.792
• Mol file: 65390-74-1.mol

Synonyms:(η-cyclo-octa-1,5-diene)tris(N,N-dimethylhydrazine)hydridoruthenium(II) tetraphenylborate

Chemical Property of (η-cyclo-octa-1,5-diene)tris(N,N-dimethylhydrazine)hydridoruthenium(II) tetraphenylborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η-cyclo-octa-1,5-diene)tris(N,N-dimethylhydrazine)hydridoruthenium(II) tetraphenylborate

There total 2 articles about (η-cyclo-octa-1,5-diene)tris(N,N-dimethylhydrazine)hydridoruthenium(II) tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

dichloro(1,5-cyclooctadiene)ruthenium(II) + sodium tetraphenyl borate (143-66-8) + N,N-Dimethylhydrazine (57-14-7) → (cyclo-octa-1,5-diene)tris(N',N'-dimethylhydrazine)hydridorutheniumtetraphenylborate (65390-74-1)

Guidance literature:

With methanol; In methanol; water; addn. of excess Me2NNH2 to suspn. of Ru-complex in MeOH, boiling for 20 min (dissoln.), addn. of excess aq. NaBPh4; crystn.; can be recrystallized (aq. MeOH contg. Me2NNH2); elem. anal.;

DOI:10.1039/DT9770001809

Reference yield: 43.0%

dichloro(1,5-cyclooctadiene)ruthenium(II) + sodium tetraphenyl borate (143-66-8) + N,N-Dimethylhydrazine (57-14-7) → (cyclo-octa-1,5-diene)tris(N',N'-dimethylhydrazine)hydridorutheniumtetraphenylborate (65390-74-1) + [RuH(1,5-cod)(NH3)(NH2NMe2)2](BPh4) + [RuCl(1,5-cod)(NH3)2(NH2NMe2)](BPh4)

Guidance literature:

dichloro(1,5-cyclooctadiene)ruthenium(II); N,N-Dimethylhydrazine; In methanol; water; for 0.5h; Reflux; Inert atmosphere; Schlenk technique;

sodium tetraphenyl borate; In methanol; water; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.ica.2015.08.019

Reference yield: 88.0%

phenylphosphonous acid dimethyl ester (2946-61-4) + (cyclo-octa-1,5-diene)tris(N',N'-dimethylhydrazine)hydridorutheniumtetraphenylborate (65390-74-1) → [RuH(PMe2Ph)5](PF6) (37766-60-2)

Guidance literature:

In methanol; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.ica.2015.08.019

upstream raw materials:

sodium tetraphenyl borate

N,N-Dimethylhydrazine

Downstream raw materials:

[RuH(P(OCH₃)2C₆H₅)5]⁽¹⁺⁾

RuH(P(OC₂H₅)2C₆H₅)5⁽¹⁺⁾

Ru(C₈H₁₁)(C₈H₁₀)⁽¹⁺⁾*B(C₆H₅)4^(1-) = [Ru(C₈H₁₁)(C₈H₁₀)][B(C₆H₅)4]

(cyclo-octa-1,5-diene)tris(hydrazine)hydridoruthenium tetraphenylborate