Terbium iodide (TbI3)

Base Information

• Chemical Name: Terbium iodide (TbI3)
• CAS No.: 13813-40-6
• Molecular Formula: I3Tb
• Molecular Weight: 539.639
• European Community (EC) Number: 237-469-8
• DSSTox Substance ID: DTXSID0065644
• Wikipedia: Terbium(III) iodide,Terbium(III)_iodide
• Wikidata: Q3791589
• Mol file: 13813-40-6.mol

Synonyms:Terbium iodide;Terbium iodide (TbI3);13813-40-6;triiodoterbium;Terbium(III) iodide;Terbium triiodide;TbI3;Terbium( cento) iodide;DTXSID0065644;Terbium(III) iodide, ultra dry;EINECS 237-469-8;MFCD00049573;Q3791589;Terbium(III) iodide, anhydrous, flakes, 99.99% trace metals basis

Chemical Property of Terbium iodide (TbI3)

Chemical Property:

• Melting Point: 946°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.65710
• Sensitive.: Hygroscopic
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 539.6388
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

97% ^*data from raw suppliers

Terbium(III) iodide anhydrous, flakes, 99.99% trace metals basis ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 42/43-63
• Safety Statements: 22-26-36

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Rare Earth Metals
• Canonical SMILES: I[Tb](I)I

Technology Process of Terbium iodide (TbI3)

There total 6 articles about Terbium iodide (TbI3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[Tb(water)9](I)3 → terbium(III) iodide (13813-40-6)

Guidance literature:

In neat (no solvent, solid phase); byproducts: H2O; Schlenk techniques; heating Tb compd. under vacuum (1E-3 Torr);

DOI:10.1016/j.poly.2010.02.027

Reference yield:

terbium + iodine (7553-56-2,12190-71-5,8031-47-8) → terbium(III) iodide (13813-40-6)

Guidance literature:

In tetrahydrofuran; (N2); molar ratio of Tb:I2 2:3; clear THF soln. of triiodide obtained by filtration or decanting;

Reference yield:

terbium → terbium(III) iodide (13813-40-6)

Guidance literature:

With iodine; In neat (no solvent); direct reaction of metal with iodine in a two-section ampoule at 800-900°C; sublimation at 1100-1200°C;

upstream raw materials:

iodine

aluminium

1,2-Diiodoethane

Downstream raw materials:

[Tb(η5-C5Me4CH2C12H7NPh)2I(THF]