(E)-benzyl 1-phenylethylidenecarbamate

Base Information

Chemical Name:(E)-benzyl 1-phenylethylidenecarbamate
CAS No.:909906-72-5
Molecular Formula:C₁₆H₁₅NO₂
Molecular Weight:253.301
Hs Code.:

Synonyms:(E)-benzyl 1-phenylethylidenecarbamate

Suppliers and Price of (E)-benzyl 1-phenylethylidenecarbamate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (E)-benzyl 1-phenylethylidenecarbamate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (E)-benzyl 1-phenylethylidenecarbamate

There total 5 articles about (E)-benzyl 1-phenylethylidenecarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 123660-45-7
(α-methylbenzyl)carbamic acid benzyl ester

: 909906-72-5
(E)-benzyl 1-phenylethylidenecarbamate

Guidance literature:: With n-butyllithium; N-(tert-butyl)benzenesulfinimidoyl chloride; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;
DOI:10.1039/b605882e

Reference yield:

: 75-16-1
methylmagnesium bromide

: 100-47-0
benzonitrile

: 501-53-1,94274-21-2
benzyl chloroformate

: 909906-72-5
(E)-benzyl 1-phenylethylidenecarbamate

: 697301-71-6
(1-phenylvinyl)carbamic acid benzyl ester

Guidance literature:: methylmagnesium bromide; benzonitrile; copper(I) bromide; In tetrahydrofuran; diethyl ether; at 0 ℃; for 2.5h; Heating / reflux;

With lithium chloride; In tetrahydrofuran; diethyl ether; at 20 ℃; for 1h;

benzyl chloroformate; In tetrahydrofuran; diethyl ether; at 0 - 20 ℃; for 17h;

Reference yield:

: 98-85-1,13323-81-4
1-Phenylethanol

: 909906-72-5
(E)-benzyl 1-phenylethylidenecarbamate

Guidance literature:: Multi-step reaction with 3 steps

1: diphenyl phosphoryl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene / toluene / 0 °C

2: ([2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)(μ-CO))2 / tetrahydrofuran / 20 °C / Irradiation; Inert atmosphere; Schlenk technique

3: tetrahydrofuran / 3 h / 50 °C / Inert atmosphere; Irradiation; Schlenk technique

With ([2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)(μ-CO))2; diphenyl phosphoryl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; toluene;
DOI:10.1002/adsc.201601406