Technology Process of (E)-benzyl 1-phenylethylidenecarbamate
There total 5 articles about (E)-benzyl 1-phenylethylidenecarbamate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
n-butyllithium; N-(tert-butyl)benzenesulfinimidoyl chloride;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 0.5h;
DOI:10.1039/b605882e
- Guidance literature:
-
methylmagnesium bromide; benzonitrile;
copper(I) bromide;
In
tetrahydrofuran; diethyl ether;
at 0 ℃;
for 2.5h;
Heating / reflux;
With
lithium chloride;
In
tetrahydrofuran; diethyl ether;
at 20 ℃;
for 1h;
benzyl chloroformate;
In
tetrahydrofuran; diethyl ether;
at 0 - 20 ℃;
for 17h;
- Guidance literature:
-
Multi-step reaction with 3 steps
1: diphenyl phosphoryl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene / toluene / 0 °C
2: ([2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)(μ-CO))2 / tetrahydrofuran / 20 °C / Irradiation; Inert atmosphere; Schlenk technique
3: tetrahydrofuran / 3 h / 50 °C / Inert atmosphere; Irradiation; Schlenk technique
With
([2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)(μ-CO))2; diphenyl phosphoryl azide; 1,8-diazabicyclo[5.4.0]undec-7-ene;
In
tetrahydrofuran; toluene;
DOI:10.1002/adsc.201601406
