2-chloro-1,3-bis(diisopropylphenyl)-1,3-dihydro-1,3,2-diazaphosphol

Base Information

• Chemical Name: 2-chloro-1,3-bis(diisopropylphenyl)-1,3-dihydro-1,3,2-diazaphosphol
• CAS No.: 884639-92-3
• Molecular Formula: C₂₆H₃₆ClN₂P
• Molecular Weight: 443.012
• Mol file: 884639-92-3.mol

Synonyms:2-chloro-1,3-bis(diisopropylphenyl)-1,3-dihydro-1,3,2-diazaphosphol

Chemical Property of 2-chloro-1,3-bis(diisopropylphenyl)-1,3-dihydro-1,3,2-diazaphosphol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-chloro-1,3-bis(diisopropylphenyl)-1,3-dihydro-1,3,2-diazaphosphol

There total 9 articles about 2-chloro-1,3-bis(diisopropylphenyl)-1,3-dihydro-1,3,2-diazaphosphol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) + 1,1,3,3-tetradiisopropylphenyl-1,1,3,3-tetrahydro-2,2-bi-1,3,2-diazaphosphole (1151469-21-4) → 2-chloro-1,3-bis(diisopropylphenyl)-1,3-dihydro-1,3,2-diazaphosphol (884639-92-3) + C52H72Cl2N4P2Pd2

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 0.25h; Inert atmosphere;

DOI:10.1021/ic400886b

Reference yield: 43.0%

2-hydrido-1,3-bis(2,6-diisopropylphenyl)-1,3,2-diazaphosphalene + dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) → 2-chloro-1,3-bis(diisopropylphenyl)-1,3-dihydro-1,3,2-diazaphosphol (884639-92-3) + C52H72Cl2N4P2Pd2

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 0.25h; Inert atmosphere;

DOI:10.1021/ic400886b

Reference yield: 41.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1,1,3,3-tetradiisopropylphenyl-1,1,3,3-tetrahydro-2,2-bi-1,3,2-diazaphosphole (1151469-21-4) → 2-chloro-1,3-bis(diisopropylphenyl)-1,3-dihydro-1,3,2-diazaphosphol (884639-92-3) + bis(1,3-di(2,6-diisopropylphenyl)-1,3,2-diazaphospholenium)diplatinum(0) dichloride

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/ic400886b

upstream raw materials:

(1E,2E)-N¹,N²-bis(2,6-diisopropylphenyl)-ethane-1,2-diimine

1,1,3,3-tetradiisopropylphenyl-1,1,3,3-tetrahydro-2,2-bi-1,3,2-diazaphosphole

triphenylphosphine

dichloro(1,5-cyclooctadiene)palladium(II)

Downstream raw materials:

1,3-bis(2,6-diisopropylphenyl)-1,3,2-diazaphospholenium trifluoromethanesulfonate

1,1,3,3-tetradiisopropylphenyl-1,1,3,3-tetrahydro-2,2-bi-1,3,2-diazaphosphole

C₃₈H₅₆N₂P₂

C₂₆H₃₈N₂P