3,4,6-tri-O-benzyl-2-benzyloxycarbonylamino-2-deoxy-α-D-glucopyranosyl bis(dimethylamido)phosphate

Base Information

Chemical Name:3,4,6-tri-O-benzyl-2-benzyloxycarbonylamino-2-deoxy-α-D-glucopyranosyl bis(dimethylamido)phosphate
CAS No.:134637-15-3
Molecular Formula:C₃₉H₄₈N₃O₈P
Molecular Weight:717.799
Hs Code.:

Synonyms:3,4,6-tri-O-benzyl-2-benzyloxycarbonylamino-2-deoxy-α-D-glucopyranosyl bis(dimethylamido)phosphate

Suppliers and Price of 3,4,6-tri-O-benzyl-2-benzyloxycarbonylamino-2-deoxy-α-D-glucopyranosyl bis(dimethylamido)phosphate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3,4,6-tri-O-benzyl-2-benzyloxycarbonylamino-2-deoxy-α-D-glucopyranosyl bis(dimethylamido)phosphate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3,4,6-tri-O-benzyl-2-benzyloxycarbonylamino-2-deoxy-α-D-glucopyranosyl bis(dimethylamido)phosphate

There total 1 articles about 3,4,6-tri-O-benzyl-2-benzyloxycarbonylamino-2-deoxy-α-D-glucopyranosyl bis(dimethylamido)phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1605-65-8
N,N,N',N'-Tetramethylphosphorodiamidic chloride

: 121037-23-8
3,4,6-tri-O-benzyloxycarbonylamino-2-deoxy-D-glucopyranose

: 134637-15-3
3,4,6-tri-O-benzyl-2-benzyloxycarbonylamino-2-deoxy-α-D-glucopyranosyl bis(dimethylamido)phosphate

Guidance literature:: With n-butyllithium; Yield given. Multistep reaction; 1.) THF, -78 deg C, 2.) HMPA, -10 deg C, 1 h;
DOI:10.1016/S0040-4039(00)74296-1

Reference yield: 74.0%

: 23363-33-9
4'-demethyl-4'-O-(benzoyloxycarbonyl)epipodophyllotoxin

: 134637-15-3
3,4,6-tri-O-benzyl-2-benzyloxycarbonylamino-2-deoxy-α-D-glucopyranosyl bis(dimethylamido)phosphate

: 134637-16-4
C₆₄H₆₁NO₁₆

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at -8 ℃; for 0.25h;
DOI:10.1016/S0040-4039(00)74296-1

Reference yield:

: 134637-15-3
3,4,6-tri-O-benzyl-2-benzyloxycarbonylamino-2-deoxy-α-D-glucopyranosyl bis(dimethylamido)phosphate

: 111310-71-5
(5R,5aR,8aR,9S)-9-((2R,3R,4R,5S,6R)-3-Amino-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-5-(4-hydroxy-3,5-dimethoxy-phenyl)-5,8,8a,9-tetrahydro-5aH-furo[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6-one

Guidance literature:: Multi-step reaction with 2 steps

1: 74 percent / BF₃*OEt₂ / CH₂Cl₂ / 0.25 h / -8 °C

2: H₂ / Pd(OH)2/C / methanol; ethyl acetate / 12 h

With boron trifluoride diethyl etherate; hydrogen; palladium dihydroxide; In methanol; dichloromethane; ethyl acetate;
DOI:10.1016/S0040-4039(00)74296-1