[(pentamethylcyclopentadienyl)IrCl(triphenyl phosphite)2]OTf

Base Information

Chemical Name:[(pentamethylcyclopentadienyl)IrCl(triphenyl phosphite)2]OTf
CAS No.:240817-54-3
Molecular Formula:CF₃O₃S*C₄₆H₄₅ClIrO₆P₂
Molecular Weight:1132.55
Hs Code.:

Synonyms:[(pentamethylcyclopentadienyl)IrCl(triphenyl phosphite)2]OTf

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Chemical Property of [(pentamethylcyclopentadienyl)IrCl(triphenyl phosphite)2]OTf

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Technology Process of [(pentamethylcyclopentadienyl)IrCl(triphenyl phosphite)2]OTf

There total 1 articles about [(pentamethylcyclopentadienyl)IrCl(triphenyl phosphite)2]OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 101-02-0
triphenyl phosphite

: 12354-84-6,12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

: 2923-28-6
silver trifluoromethanesulfonate

: 240817-54-3
[(pentamethylcyclopentadienyl)IrCl(triphenyl phosphite)2]OTf

Guidance literature:: In chloroform; byproducts: AgCl; (Ar); ligand added to complex soln., stirred for 1 h, Ag salt added, stirred for 16 h; filtered, evapd., washed (hexane); elem. anal.;
DOI:10.1021/om000718n

Reference yield: 95.0%

: 107-10-8,42939-71-9
propylamine

: 240817-54-3
[(pentamethylcyclopentadienyl)IrCl(triphenyl phosphite)2]OTf

: [(C₅(CH₃)4CH₂NHC₃H₇)Ir(P(C₆H₅)3)2]

Guidance literature:: With n-C₄H₉Li; In hexane; triethylamine; (Ar); excess of PrNH2 added to complex suspn. in Et3N, 2 equiv. BuLi/hexane added at -50°C, warmed slowly to room temp., stirred; volatiles removed, residue extd. (hexane), solvent evapd.; elem. anal.;
DOI:10.1021/om000718n

Reference yield: 93.0%

: 240817-54-3
[(pentamethylcyclopentadienyl)IrCl(triphenyl phosphite)2]OTf

: 107-18-6
allyl alcohol

: 321862-91-3
[(C₅(CH₃)4CH₂OCH₂CHCH₂)Ir(P(OC₆H₅)3)2]

Guidance literature:: With sodium tert-butoxide; In further solvent(s); (Ar); alc. added to mixt. of complex and 2 equiv. NaO(t)Bu at room temp., stirred; volatiles removed, residue extd. (Et2O), solvent evapd.; elem. anal.;
DOI:10.1021/om000718n