2-(4-Nitro-phenylselanyl)-2-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethylamine

Base Information

Chemical Name:2-(4-Nitro-phenylselanyl)-2-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethylamine
CAS No.:121056-93-7
Molecular Formula:C₃₂H₅₆N₂O₅SeSi₃
Molecular Weight:712.024
Hs Code.:

Synonyms:2-(4-Nitro-phenylselanyl)-2-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethylamine

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Chemical Property of 2-(4-Nitro-phenylselanyl)-2-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethylamine

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Technology Process of 2-(4-Nitro-phenylselanyl)-2-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethylamine

There total 9 articles about 2-(4-Nitro-phenylselanyl)-2-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 121056-92-6
{2-(4-Nitro-phenylselanyl)-2-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-carbamic acid tert-butyl ester

: 121056-93-7
2-(4-Nitro-phenylselanyl)-2-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethylamine

Guidance literature:: With trifluoroacetic acid; In dichloromethane; for 1h; Yield given; Ambient temperature;
DOI:10.1021/ja00198a040

Reference yield:

: 99-24-1
methyl galloate

: 121056-93-7
2-(4-Nitro-phenylselanyl)-2-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethylamine

Guidance literature:: Multi-step reaction with 8 steps

1: 93 percent / imidazole / dimethylformamide / 20 h

2: 79 percent / LiAlH₄ / tetrahydrofuran / 3 h / Heating

3: 75 percent / pyridinium chlorochromate / CH₂Cl₂ / 4 h / Ambient temperature

4: ZnI₂ / 4 h / Ambient temperature

5: LiAlH₄ / tetrahydrofuran / 3 h / Ambient temperature

6: 67 percent / CH₂Cl₂ / 0.5 h

7: 75 percent / tri-n-butylphosphine / tetrahydrofuran / 3 h / Ambient temperature

8: trifluoroacetic acid / CH₂Cl₂ / 1 h / Ambient temperature

With 1H-imidazole; lithium aluminium tetrahydride; tributylphosphine; pyridinium chlorochromate; trifluoroacetic acid; zinc(II) iodide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00198a040

Reference yield:

: 121056-97-1
methyl 3,4,5-tris<(tert-butyldimethylsilyl)oxy>benzoate

: 121056-93-7
2-(4-Nitro-phenylselanyl)-2-[3,4,5-tris-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethylamine

Guidance literature:: Multi-step reaction with 7 steps

1: 79 percent / LiAlH₄ / tetrahydrofuran / 3 h / Heating

2: 75 percent / pyridinium chlorochromate / CH₂Cl₂ / 4 h / Ambient temperature

3: ZnI₂ / 4 h / Ambient temperature

4: LiAlH₄ / tetrahydrofuran / 3 h / Ambient temperature

5: 67 percent / CH₂Cl₂ / 0.5 h

6: 75 percent / tri-n-butylphosphine / tetrahydrofuran / 3 h / Ambient temperature

7: trifluoroacetic acid / CH₂Cl₂ / 1 h / Ambient temperature

With lithium aluminium tetrahydride; tributylphosphine; pyridinium chlorochromate; trifluoroacetic acid; zinc(II) iodide; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja00198a040