(η6-C6H5PPhMe)Mo(PPh2Me)3

Base Information

Chemical Name:(η6-C6H5PPhMe)Mo(PPh2Me)3
CAS No.:84430-77-3
Molecular Formula:C₅₂H₅₂MoP₄
Molecular Weight:896.82
Hs Code.:

Synonyms:(η6-C6H5PPhMe)Mo(PPh2Me)3

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Chemical Property of (η6-C6H5PPhMe)Mo(PPh2Me)3

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Technology Process of (η6-C6H5PPhMe)Mo(PPh2Me)3

There total 2 articles about (η6-C6H5PPhMe)Mo(PPh2Me)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: molybdenum pentachloride

: 7439-95-4
magnesium

: 1486-28-8
diphenyl(methyl)phosphine

: trans-bis(dinitrogen)(PMePh₂)4 molybdenum

: 84430-77-3
(η6-C6H5PPhMe)Mo(PPh2Me)3

Guidance literature:: With N₂; I₂; In tetrahydrofuran; N2-atmosphere; addn. of Mo2Cl10 and PMePh2 to THF (ice bath), addn. of Mg (activated with I2), stirring (90 min, ice bath; then 45 min, withoutcooling); decantation, evapn. (vac.), dissoln. in C6H6, filtration (Celite), partial evapn. (vac., pptn.), filtration, washing (MeOH), drying (vac., 30 min); elem. anal.; can be recrystallized (C6H6/MeOH);

Reference yield: 75.0%

: molybdenum pentachloride

: 1486-28-8
diphenyl(methyl)phosphine

: 84430-77-3
(η6-C6H5PPhMe)Mo(PPh2Me)3

Guidance literature:: With magnesium; In tetrahydrofuran; Mo2Cl10 dissolved in soln. of PMePh2 in THF under Ar or in vac., activated Mg added, stirred for 45 min at 25°C; filtered, evapd., extd. with benzene, filtered through celite, concd. in vac., treated with methanol, recrystd. (benzene/methanol) in presence of excess PMePh2; elem. anal.;
DOI:10.1016/S0022-328X(00)87042-4

Reference yield: 95.0%

: 21205-91-4
9-borabicyclo[3.3.1]nonane dimer

: 84430-77-3
(η6-C6H5PPhMe)Mo(PPh2Me)3

: 89486-69-1
Mo(C₆H₅P(BH(C₈H₁₄))(CH₃)(C₆H₅))N₂(P(CH₃)(C₆H₅)2)2

: 89486-71-5
CH₃(C₆H₅)2PBH(C₈H₁₄)

Guidance literature:: With nitrogen; In hexane; Mo-complex was stirred under N2 in soln. of dimeric borane (molar ratio1:2.5) in dry hexanes for 20 h; filtered, washed with cold hexanes, dissolved in benzene satd. with (9-BBN)2, filtered, concd., hexanes added carefully, cooled; elem. anal.;