Mo(η6-PhPMePh)(dppe)(PMePh2)

Base Information

• Chemical Name: Mo(η6-PhPMePh)(dppe)(PMePh2)
• CAS No.: 88727-06-4
• Molecular Formula: C₅₂H₅₀MoP₄
• Molecular Weight: 894.804
• Mol file: 88727-06-4.mol

Synonyms:

Chemical Property of Mo(η6-PhPMePh)(dppe)(PMePh2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mo(η6-PhPMePh)(dppe)(PMePh2)

There total 1 articles about Mo(η6-PhPMePh)(dppe)(PMePh2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

(η6-C6H5PPhMe)Mo(PPh2Me)3 (84430-77-3) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → Mo(η6-PhPMePh)(dppe)(PMePh2) (88727-06-4)

Guidance literature:

In tetrahydrofuran; (N2); solid ligand was added to soln. of Mo complex; after reacting 30 min soln. was concd. and pptd. with MeOH; elem. anal.;

DOI:10.1016/0022-328X(83)87024-7

Reference yield: 70.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + Mo(η6-PhPMePh)(dppe)(PMePh2) (88727-06-4) → Mo(C6H5P(RhCl(C8H12))CH3(C6H5))((C6H5)2PCH2)2PCH3(C6H5)2

Guidance literature:

In tetrahydrofuran; (N2); to stirred soln. of Mo complex was added dropwise soln. of Rh complex within 5 min, stirring was continued for 30 min; soln. was concd. and pptd. with MeOH, ppt. was filtered off, recrystd. from THF/MeOH and dried in vac.; elem. anal.;

DOI:10.1016/0022-328X(83)87024-7

Reference yield: 64.0%

Mo(η6-PhPMePh)(dppe)(PMePh2) (88727-06-4) → Mo(η6-PhPMePh)(dppe)(CO) (88727-07-5)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; (N2); soln. of Mo complex was refluxed for 72 h under CO atmosphere (1 atm); soln. was concd. and pptd. with MeOH; recrystn. from benzene/MeOH; product obtained only in a inseparable 80:20 mixt. with educt;

DOI:10.1016/0022-328X(83)87024-7

upstream raw materials:

(η6-C6H5PPhMe)Mo(PPh2Me)3

1,2-bis-(diphenylphosphino)ethane

Downstream raw materials:

Mo(η6-PhPMePh)(dppe)(P(OMe)3)

Mo(η6-PhP(a){Mo(CO)5}MePh)(dppe)(P(d)MePh2)

Mo(η6-PhPMePh)(dppe)(CO)

Mo(PCH₃(C₆H₅)2)(CNC(CH₃)3)(((C₆H₅)2PCH₂)2)