(iron)2(S₂C₂(Smethyl)2)(carbonyl)4((phenyl)3phosphine)2

Base Information

• Chemical Name: (iron)2(S₂C₂(Smethyl)2)(carbonyl)4((phenyl)3phosphine)2
• CAS No.: 97390-97-1
• Molecular Formula: C₄₄H₃₆Fe₂O₄P₂S₄
• Molecular Weight: 930.673
• Mol file: 97390-97-1.mol

Synonyms:(iron)2(S₂C₂(Smethyl)2)(carbonyl)4((phenyl)3phosphine)2

Chemical Property of (iron)2(S₂C₂(Smethyl)2)(carbonyl)4((phenyl)3phosphine)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (iron)2(S₂C₂(Smethyl)2)(carbonyl)4((phenyl)3phosphine)2

There total 5 articles about (iron)2(S₂C₂(Smethyl)2)(carbonyl)4((phenyl)3phosphine)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

sodium tetrahydroborate (16940-66-2) + iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)iodide (72598-18-6) → (iron)2(S2C2(Smethyl)2)(carbonyl)4((phenyl)3phosphine)2 (97390-97-1)

Guidance literature:

In tetrahydrofuran; Addn. of NaBH4 to (Fe(CS2CH3)(CO)2(P(C6H5)3)2)I in THF at room temp. (N2). After stirring for 2 h purple product is obtained.; Solvent evapn. under reduced pressure, silica gel chromy. under N2 with ether and then with THF, recrystn. (THF/hexane), elem. anal.;

DOI:10.1021/om00091a013

Reference yield: 40.0%

iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)iodide (72598-18-6) → (iron)2(S2C2(Smethyl)2)(carbonyl)4((phenyl)3phosphine)2 (97390-97-1) + iron((methyl)2tetrathiooxalate)(carbonyl)2((phenyl)3phosphine) (97390-96-0)

Guidance literature:

With Na#Hg; In tetrahydrofuran; Addn. of (Fe(η2-CS2Me)(CO)2(PPh3)2)I in THF to sodium amalgam (N2), stirring at room temp.; Monitored by TLC, after 20 min a mixt. of 2 complexes is obtained that are sepd. by column chromy. (eluents: pentane-ether, THF), crystn.(THF-hexane, elem. anal.;

DOI:10.1021/om00091a013

Reference yield:

iron(η2-CS2)(carbonyl)2(PPh3)2 (64424-68-6) → (iron)2(S2C2(Smethyl)2)(carbonyl)4((phenyl)3phosphine)2 (97390-97-1)

Guidance literature:

Multi-step reaction with 2 steps

1: CH₃I / dichloromethane

2: tetrahydrofuran

With CH₃I; In tetrahydrofuran; dichloromethane;

DOI:10.1021/om00091a013

upstream raw materials:

sodium tetrahydroborate

iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)2{PF6}

iron(η2-CS2(methyl))(carbonyl)2((phenyl)3phosphine)iodide

bis(triphenylphosphoranylidene)ammonium borohydride

Downstream raw materials:

Fe(S₂C₂(SCH₃)2)(CO)2(P(C₆H₅)3)

iron((methyl)2tetrathiooxalate)(carbonyl)2((phenyl)3phosphine)