(1S,2S,6R)-1-[2-(3-isopropyl-2-methoxyphenyl)ethyl]-6-methyl-7-oxabicyclo[4.1.0]heptan-2-ol

Base Information

Chemical Name:(1S,2S,6R)-1-[2-(3-isopropyl-2-methoxyphenyl)ethyl]-6-methyl-7-oxabicyclo[4.1.0]heptan-2-ol
CAS No.:1338951-76-0
Molecular Formula:C₁₉H₂₈O₃
Molecular Weight:304.43
Hs Code.:

Synonyms:(1S,2S,6R)-1-[2-(3-isopropyl-2-methoxyphenyl)ethyl]-6-methyl-7-oxabicyclo[4.1.0]heptan-2-ol

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Chemical Property of (1S,2S,6R)-1-[2-(3-isopropyl-2-methoxyphenyl)ethyl]-6-methyl-7-oxabicyclo[4.1.0]heptan-2-ol

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Technology Process of (1S,2S,6R)-1-[2-(3-isopropyl-2-methoxyphenyl)ethyl]-6-methyl-7-oxabicyclo[4.1.0]heptan-2-ol

There total 2 articles about (1S,2S,6R)-1-[2-(3-isopropyl-2-methoxyphenyl)ethyl]-6-methyl-7-oxabicyclo[4.1.0]heptan-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1338951-75-9
(1S)-2-[2-(3-isopropyl-2-methoxyphenyl)ethyl]-3-methylcyclohex-2-en-1-ol

: 1338951-76-0
(1S,2S,6R)-1-[2-(3-isopropyl-2-methoxyphenyl)ethyl]-6-methyl-7-oxabicyclo[4.1.0]heptan-2-ol

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 1h; optical yield given as %ee; Inert atmosphere;
DOI:10.1016/j.tet.2011.08.050

Reference yield:

: 1245920-23-3
2-[2-(3-isopropyl-2-methoxyphenyl)ethyl]-3-methylcyclohex-2-en-1-one

: 1338951-76-0
(1S,2S,6R)-1-[2-(3-isopropyl-2-methoxyphenyl)ethyl]-6-methyl-7-oxabicyclo[4.1.0]heptan-2-ol

Guidance literature:: Multi-step reaction with 2 steps

1: dimethylsulfide borane complex; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole / tetrahydrofuran / 1 h / 0 °C / Inert atmosphere

2: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 0 °C / Inert atmosphere

With dimethylsulfide borane complex; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.tet.2011.08.050