Phosphoric acid diphenyl ester (1R,2R,3S,4S)-2,3,4-trihydroxy-cyclopentylmethyl ester

Base Information

Chemical Name:Phosphoric acid diphenyl ester (1R,2R,3S,4S)-2,3,4-trihydroxy-cyclopentylmethyl ester
CAS No.:180524-79-2
Molecular Formula:C₁₈H₂₁O₇P
Molecular Weight:380.334
Hs Code.:

Synonyms:Phosphoric acid diphenyl ester (1R,2R,3S,4S)-2,3,4-trihydroxy-cyclopentylmethyl ester

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Chemical Property of Phosphoric acid diphenyl ester (1R,2R,3S,4S)-2,3,4-trihydroxy-cyclopentylmethyl ester

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Technology Process of Phosphoric acid diphenyl ester (1R,2R,3S,4S)-2,3,4-trihydroxy-cyclopentylmethyl ester

There total 3 articles about Phosphoric acid diphenyl ester (1R,2R,3S,4S)-2,3,4-trihydroxy-cyclopentylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 180524-78-1
Phosphoric acid (3aR,4R,6S,6aS)-6-hydroxy-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-ylmethyl ester diphenyl ester

: 180524-79-2
Phosphoric acid diphenyl ester (1R,2R,3S,4S)-2,3,4-trihydroxy-cyclopentylmethyl ester

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; for 21h; Ambient temperature;
DOI:10.1016/0968-0896(96)00090-9

Reference yield:

: 115509-13-2
(3aR,6aR)-2,2-Dimethyl-3a,6a-dihydro-cyclopenta[1,3]dioxol-4-one

: 180524-79-2
Phosphoric acid diphenyl ester (1R,2R,3S,4S)-2,3,4-trihydroxy-cyclopentylmethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 80 percent / benzophenone / 1 h / Irradiation

2: 21 percent / sodium triacetoxyborohydride / benzene / 48 h / Ambient temperature

3: 60 percent / diisopropylethylamine, DMAP / CH₂Cl₂ / 72 h / Ambient temperature

4: 99 percent / 1N aq. HCl / tetrahydrofuran / 21 h / Ambient temperature

With hydrogenchloride; dmap; benzophenone; sodium tris(acetoxy)borohydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; benzene;
DOI:10.1016/0968-0896(96)00090-9

Reference yield:

: 132575-63-4
(3aR,6R,6aR)-6-(hydroxymethyl)-2,2-dimethyldihydro-3aH-cyclopenta[d][1,3]dioxol-4(5H)-one

: 180524-79-2
Phosphoric acid diphenyl ester (1R,2R,3S,4S)-2,3,4-trihydroxy-cyclopentylmethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 21 percent / sodium triacetoxyborohydride / benzene / 48 h / Ambient temperature

2: 60 percent / diisopropylethylamine, DMAP / CH₂Cl₂ / 72 h / Ambient temperature

3: 99 percent / 1N aq. HCl / tetrahydrofuran / 21 h / Ambient temperature

With hydrogenchloride; dmap; sodium tris(acetoxy)borohydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; benzene;
DOI:10.1016/0968-0896(96)00090-9