23-O-(p-nitrobenzenesulfonyl)-9-O-[p-(trifluoroethyldiazirinyl)benzoyl]-21-deoxyconcanolide A

Base Information

Chemical Name:23-O-(p-nitrobenzenesulfonyl)-9-O-[p-(trifluoroethyldiazirinyl)benzoyl]-21-deoxyconcanolide A
CAS No.:403815-33-8
Molecular Formula:C₅₄H₇₀F₃N₃O₁₄S
Molecular Weight:1074.22
Hs Code.:

Synonyms:23-O-(p-nitrobenzenesulfonyl)-9-O-[p-(trifluoroethyldiazirinyl)benzoyl]-21-deoxyconcanolide A

Suppliers and Price of 23-O-(p-nitrobenzenesulfonyl)-9-O-[p-(trifluoroethyldiazirinyl)benzoyl]-21-deoxyconcanolide A

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Chemical Property of 23-O-(p-nitrobenzenesulfonyl)-9-O-[p-(trifluoroethyldiazirinyl)benzoyl]-21-deoxyconcanolide A

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Technology Process of 23-O-(p-nitrobenzenesulfonyl)-9-O-[p-(trifluoroethyldiazirinyl)benzoyl]-21-deoxyconcanolide A

There total 5 articles about 23-O-(p-nitrobenzenesulfonyl)-9-O-[p-(trifluoroethyldiazirinyl)benzoyl]-21-deoxyconcanolide A which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: 85559-46-2
4-[3-(trifluoromethyl)-3H-diazirin-3-yl]benzoic acid

: 161888-65-9
23-O-(p-nitrobenzenesulfonyl)-21-deoxyconcanolide A

: 403815-33-8
23-O-(p-nitrobenzenesulfonyl)-9-O-[p-(trifluoroethyldiazirinyl)benzoyl]-21-deoxyconcanolide A

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 18h;
DOI:10.1002/1099-0690(200112)2001:23<4525::AID-EJOC4525>3.0.CO;2-S

Reference yield:

: 80890-47-7
concanamycin A

: 403815-33-8
23-O-(p-nitrobenzenesulfonyl)-9-O-[p-(trifluoroethyldiazirinyl)benzoyl]-21-deoxyconcanolide A

Guidance literature:: Multi-step reaction with 5 steps

1: 96 percent / FeCl₃ / 0.25 h

2: 46 percent / NaBH₃CN; HCl / ethanol / 4 h / 20 °C

3: 34 percent / p-TsOH / acetonitrile; H₂O / 24 h / 38 °C

4: 89 percent / NEt₃; DMAP / CH₂Cl₂ / 2 h / 0 °C

5: 46 percent / DCC; DMAP / CH₂Cl₂ / 18 h / 20 °C

With hydrogenchloride; dmap; iron(III) chloride; sodium cyanoborohydride; toluene-4-sulfonic acid; triethylamine; dicyclohexyl-carbodiimide; In ethanol; dichloromethane; water; acetonitrile;
DOI:10.1002/1099-0690(200112)2001:23<4525::AID-EJOC4525>3.0.CO;2-S

Reference yield:

: 161888-61-5
21-deoxyconcanolide A

: 403815-33-8
23-O-(p-nitrobenzenesulfonyl)-9-O-[p-(trifluoroethyldiazirinyl)benzoyl]-21-deoxyconcanolide A

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / NEt₃; DMAP / CH₂Cl₂ / 2 h / 0 °C

2: 46 percent / DCC; DMAP / CH₂Cl₂ / 18 h / 20 °C

With dmap; triethylamine; dicyclohexyl-carbodiimide; In dichloromethane;
DOI:10.1002/1099-0690(200112)2001:23<4525::AID-EJOC4525>3.0.CO;2-S