C₆H₅-C{NH(CH₂)2StBu}=NC₆H₅

Base Information

• Chemical Name: C₆H₅-C{NH(CH₂)2StBu}=NC₆H₅
• CAS No.: 1361456-17-8
• Molecular Formula: C₁₉H₂₄N₂S
• Molecular Weight: 312.479
• Mol file: 1361456-17-8.mol

Synonyms:C₆H₅-C{NH(CH₂)2StBu}=NC₆H₅

Chemical Property of C₆H₅-C{NH(CH₂)2StBu}=NC₆H₅

Chemical Property:

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Technology Process of C₆H₅-C{NH(CH₂)2StBu}=NC₆H₅

There total 1 articles about C₆H₅-C{NH(CH₂)2StBu}=NC₆H₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

<2-(tert-butylthio)ethyl>amine hydrochloride (60116-77-0) + N-phenyl-benzimidoyl chloride (4903-36-0) → C6H5-C{NH(CH2)2StBu}=NC6H5 (1361456-17-8)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1039/c2dt11097k

Reference yield: 62.0%

C6H5-C{NH(CH2)2StBu}=NC6H5 (1361456-17-8) + palladium dichloride → [Ph-C{-NH(η1-C6H4)}{=N(CH2)2StBu}]PdCl (1361456-29-2)

Guidance literature:

With Et₃N; In dichloromethane; under N2; CH2Cl2 and Et3N added to ligand and PdCl2 at room temp.; stirred for 48 h; filtered; filtrate washed with deionized H2O; org. layer sepd.; dried (MgSO4); filtrate pumped to dryness; extd. with toluene; solid obtained; elem. anal.;

DOI:10.1039/c2dt11097k

Reference yield: 42.0%

C6H5-C{NH(CH2)2StBu}=NC6H5 (1361456-17-8) + palladium diacetate (3375-31-3) → Pd(C6H4NHC(C6H5)NCH2CH2SC(CH3)3)(O2CCH3) (1361456-23-6) + (Pd(C6H4NHC(C6H5)NCH2CH2SC(CH3)3)(O2CCH3))2 (1361456-33-8)

Guidance literature:

In dichloromethane; under N2; CH2Cl2 added to ligand and Pd acetate at room temp.; stirred for 12 h; filtered; filtrate pumped to dryness; extd. with Et2O; extract layered with hexane; stored at room temp. for 2 d (crystals of Pd dimer); residueafter extn. washed with acetone (mono-Pd complex); elem. anal.;

DOI:10.1039/c2dt11097k

upstream raw materials:

<2-(tert-butylthio)ethyl>amine hydrochloride

N-phenyl-benzimidoyl chloride

Downstream raw materials:

Pd(C₆H₄NHC(C₆H₅)NCH₂CH₂SC(CH₃)3)(O₂CCH₃)

(Pd(C₆H₄NHC(C₆H₅)NCH₂CH₂SC(CH₃)3)(O₂CCH₃))2

[Ph-C{-NH(η1-C6H4)}{=N(CH2)2StBu}]PdCl

Refernces