(1S,2R)-(7,7-dimethyl-2-hydroxybicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester

Base Information

Chemical Name:(1S,2R)-(7,7-dimethyl-2-hydroxybicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester
CAS No.:247078-63-3
Molecular Formula:C₁₆H₂₂O₄S
Molecular Weight:310.414
Hs Code.:

Synonyms:(1S,2R)-(7,7-dimethyl-2-hydroxybicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester

Suppliers and Price of (1S,2R)-(7,7-dimethyl-2-hydroxybicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1S,2R)-(7,7-dimethyl-2-hydroxybicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1S,2R)-(7,7-dimethyl-2-hydroxybicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester

There total 7 articles about (1S,2R)-(7,7-dimethyl-2-hydroxybicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 108885-08-1
(1S)-(7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester

: 1021299-41-1
phenyl (1S,2S,4R)-2-endo-hydroxybornane-10-sulfonate

: 41348-33-8
(1S,5R,7R)-10,10-dimethyl-4-oxa-3-thiatricyclo[5.2.1.0^1,5]decane 3,3-dioxide

: 247078-63-3
(1S,2R)-(7,7-dimethyl-2-hydroxybicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester

Guidance literature:: With sodium tetrahydroborate; In ethanol; water; at -8 ℃; for 16h;

Reference yield: 45.0%

: 108885-08-1
(1S)-(7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester

: 645-96-5
Benzeneselenol

: 247078-63-3
(1S,2R)-(7,7-dimethyl-2-hydroxybicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester

: (1R,2R)-(7,7-dimethyl-2-exo-phenylselenylbicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester

Guidance literature:: (1S)-(7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester; Benzeneselenol; With boron trifluoride; In dichloromethane; at 20 ℃; for 1h;

With triethylsilane; In dichloromethane; at 20 ℃; for 72h;
DOI:10.1016/S0040-4020(99)00507-4

Reference yield:

: 21286-54-4
Camphorsulfonyl chloride

: 247078-63-3
(1S,2R)-(7,7-dimethyl-2-hydroxybicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: 76 percent / Py / 2 h / 0 °C

2.1: BF₃*H₂O / CH₂Cl₂ / 1 h / 20 °C

2.2: 30 percent / Et₃SiH / CH₂Cl₂ / 72 h / 20 °C

With pyridine; boron trifluoride; In dichloromethane; 1.1: Substitution / 2.1: Addition / 2.2: Reduction;
DOI:10.1016/S0040-4020(99)00507-4