Ru(2,2'-bipyridine)2(3-hydroxy-2-methyl-4-thiopyrone^(1-))PF₆*CH₂Cl₂

Base Information

• Chemical Name: Ru(2,2'-bipyridine)2(3-hydroxy-2-methyl-4-thiopyrone^(1-))PF₆*CH₂Cl₂
• CAS No.: 1013397-31-3
• Molecular Formula: CH₂Cl₂*C₂₆H₂₁N₄O₂RuS*F₆P
• Molecular Weight: 784.511
• Mol file: 1013397-31-3.mol

Synonyms:Ru(2,2'-bipyridine)2(3-hydroxy-2-methyl-4-thiopyrone^(1-))PF₆*CH₂Cl₂

Chemical Property of Ru(2,2'-bipyridine)2(3-hydroxy-2-methyl-4-thiopyrone^(1-))PF₆*CH₂Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru(2,2'-bipyridine)2(3-hydroxy-2-methyl-4-thiopyrone^(1-))PF₆*CH₂Cl₂

There total 1 articles about Ru(2,2'-bipyridine)2(3-hydroxy-2-methyl-4-thiopyrone^(1-))PF₆*CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

potassium hexafluorophosphate (17084-13-8) + cis-dichloro(2,2′-bipyridine)ruthenium(II)chloride + 3-hydroxy-2-methylpyran-4(1H)-thione (23060-85-7) + dichloromethane (75-09-2) → Ru(2,2'-bipyridine)2(3-hydroxy-2-methyl-4-thiopyrone(1-))PF6*CH2Cl2 (1013397-31-3)

Guidance literature:

In ethylene glycol; (under N2, Schlenk); Ru-complex and ligand mixed with ethylene glycol, brought to 130°C, stirred for 45 min, poured into H2O, KPF6 added; vac. filtered, basic alumina column with CH2Cl2/MeCN, crystd. in CH2Cl2/Et2O; elem. anal.;

DOI:10.1021/ic7021962

upstream raw materials:

potassium hexafluorophosphate

3-hydroxy-2-methylpyran-4(1H)-thione

dichloromethane