Technology Process of (2S,3S)-4-Benzyloxy-1-methoxymethoxy-2-methyl-butane-2,3-diol
There total 5 articles about (2S,3S)-4-Benzyloxy-1-methoxymethoxy-2-methyl-butane-2,3-diol which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium osmate(VI); AD-mix-α; methanesulfonamide;
(DHQ)2-PHAL; potassium hexacyanoferrate(III);
In
water; tert-butyl alcohol;
at 0 ℃;
for 20h;
DOI:10.1016/j.tet.2006.03.066
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 100 percent / LiOH*H2O / tetrahydrofuran; H2O / 12 h / 20 °C
2: 90 percent / sodium hydride; tetrabutylammonium iodide / tetrahydrofuran; various solvent(s) / 15 h / 20 °C
3: 99 percent / AD-mix-α; K2OsO4*2H2O; methanesulfonamide / (DHQ)2-PHAL; K3Fe(CN)6 / H2O; 2-methyl-propan-2-ol / 20 h / 0 °C
With
lithium hydroxide; potassium osmate(VI); AD-mix-α; methanesulfonamide; tetra-(n-butyl)ammonium iodide; sodium hydride;
(DHQ)2-PHAL; potassium hexacyanoferrate(III);
In
tetrahydrofuran; water; tert-butyl alcohol;
DOI:10.1016/j.tet.2006.03.066
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 39 percent / SeO2; t-BuO2H; p-MeOC6H4CO2H
2: 82 percent / diisopropylethylamine / tetrahydrofuran / 12 h / 20 °C
3: 100 percent / LiOH*H2O / tetrahydrofuran; H2O / 12 h / 20 °C
4: 90 percent / sodium hydride; tetrabutylammonium iodide / tetrahydrofuran; various solvent(s) / 15 h / 20 °C
5: 99 percent / AD-mix-α; K2OsO4*2H2O; methanesulfonamide / (DHQ)2-PHAL; K3Fe(CN)6 / H2O; 2-methyl-propan-2-ol / 20 h / 0 °C
With
tert.-butylhydroperoxide; lithium hydroxide; potassium osmate(VI); AD-mix-α; selenium(IV) oxide; methanesulfonamide; tetra-(n-butyl)ammonium iodide; sodium hydride; 4-methoxybenzoic acid; N-ethyl-N,N-diisopropylamine;
(DHQ)2-PHAL; potassium hexacyanoferrate(III);
In
tetrahydrofuran; water; tert-butyl alcohol;
DOI:10.1016/j.tet.2006.03.066
