trans,cis-RuHCl(PCy₃)₂(CO)₂

Base Information

• Chemical Name: trans,cis-RuHCl(PCy₃)₂(CO)₂
• CAS No.: 55100-76-0
• Molecular Formula: C₃₈H₆₇ClO₂P₂Ru
• Molecular Weight: 754.419
• Mol file: 55100-76-0.mol

Synonyms:trans,cis-RuHCl(PCy₃)₂(CO)₂

Chemical Property of trans,cis-RuHCl(PCy₃)₂(CO)₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans,cis-RuHCl(PCy₃)₂(CO)₂

There total 4 articles about trans,cis-RuHCl(PCy₃)₂(CO)₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) (36621-70-2,40935-25-9) + carbon monoxide (201230-82-2) → trans,cis-RuHCl(PCy3)2(CO)2 (55100-76-0)

Guidance literature:

In benzene; under Ar; soln. of Ru complex in benzene stirred under CO (1 atm) at 23°C for 1 h; concd.; pptd. by addition of hexanes; repptd. from benzene-hexanes; filtered; ppt. washed with cold hexanes; dried under vac.;

DOI:10.1021/om201288p

Reference yield: 60.0%

carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) (36621-70-2,40935-25-9) → trans,cis-RuHCl(PCy3)2(CO)2 (55100-76-0)

Guidance literature:

With carbon oxide sulfide; In toluene; COS bubbling through a soln. of Ru complex in toluene, solvent removingin vacuo, white solid sepg.; purified by recrystn. from CHCl3-MeOH; identified by elem. anal., IR and NMR spectra;

DOI:10.1021/ic00135a067

Reference yield:

carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II) (36621-70-2,40935-25-9) + tricyclohexylphosphine (2622-14-2) → trans,cis-RuHCl(PCy3)2(CO)2 (55100-76-0)

Guidance literature:

With carbon oxide sulfide; In methanol; High Pressure; COS condensing into a liquid-nitrogen-cooled pressure reactor containing Ru complex, phosphine and MeOH, warming to room temp. (caution! 12 atm), COS distilling off, white solid collecting by filtration and drying in vacuo; identified by elem. anal., IR and NMR spectra;

DOI:10.1021/ic00135a067

upstream raw materials:

carbonylchlorohydridobis(tricyclohexylphosphine)ruthenium(II)

tricyclohexylphosphine

carbon monoxide

cis,cis,trans-RuCl₂(CO)2(PCy₃)2

Downstream raw materials:

RuH(OSO₂CF₃)(CO)2(P(C₆H₁₁)3)2