{meso-5,10,15,20-tetrakis{4-(methoxycarbonyl)phenyl}porphyrinato}tin(IV) dichloride

Base Information

• Chemical Name: {meso-5,10,15,20-tetrakis{4-(methoxycarbonyl)phenyl}porphyrinato}tin(IV) dichloride
• CAS No.: 144810-99-1
• Molecular Formula: C₅₂H₃₆Cl₂N₄O₈Sn
• Molecular Weight: 1034.5
• Mol file: 144810-99-1.mol

Synonyms:{meso-5,10,15,20-tetrakis{4-(methoxycarbonyl)phenyl}porphyrinato}tin(IV) dichloride

Chemical Property of {meso-5,10,15,20-tetrakis{4-(methoxycarbonyl)phenyl}porphyrinato}tin(IV) dichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {meso-5,10,15,20-tetrakis{4-(methoxycarbonyl)phenyl}porphyrinato}tin(IV) dichloride

There total 3 articles about {meso-5,10,15,20-tetrakis{4-(methoxycarbonyl)phenyl}porphyrinato}tin(IV) dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

tin(II) chloride dihdyrate (10025-69-1) + 5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin (22112-83-0) → {meso-5,10,15,20-tetrakis{4-(methoxycarbonyl)phenyl}porphyrinato}tin(IV) dichloride (144810-99-1)

Guidance literature:

With pyridine; Reflux;

DOI:10.1039/c5ra09343k

Reference yield: 74.0%

5,10,15,20-tetrakis(4-(methoxycarbonyl)phenyl)porphyrin + tin(ll) chloride → {meso-5,10,15,20-tetrakis{4-(methoxycarbonyl)phenyl}porphyrinato}tin(IV) dichloride (144810-99-1)

Guidance literature:

In pyridine; 80-90°C; 2 h;; poured into Et2O at room temp.; organic layer washed with aq. HCl; solvent removed; dissolved in CH2Cl2; washed with water; dried over Na2SO4; solvent removed; recrystd. from CH2Cl2/MeOH;;

Reference yield:

methyl 4-formylbenzoate (1571-08-0) → {meso-5,10,15,20-tetrakis{4-(methoxycarbonyl)phenyl}porphyrinato}tin(IV) dichloride (144810-99-1)

Guidance literature:

Multi-step reaction with 2 steps

1: boron trifluoride diethyl etherate; 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane

2: pyridine / Reflux

With pyridine; boron trifluoride diethyl etherate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane;

DOI:10.1039/c5ra09343k

upstream raw materials:

tin(II) chloride dihdyrate

5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin

methyl 4-formylbenzoate