22112-83-0

Basic information

• Product Name: MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER
• Synonyms: MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER;5,10,15,20-TETRAKIS-(4-METHOXYCARBONYLPHENYL)-21,23H-PORPHYRIN;RARECHEM AS SA 0036;TETRAMETHYL MESO-TETRAPHENYLPORPHINE-4,4',4'',4'''-TETRACARBOXYLATE;5,10,15,20-Tetra(4-carboxyphenyl)porphine tetramethyl ester;5,10,15,20-meso-Tetrakis[4-(methoxycarbonyl)phenyl]porphyrin;Tetramethyl 4,4',4'',4'''-(5,10,15,20-porphyrintetrayl)tetrabenzo ate
• CAS NO: 22112-83-0
• Molecular Formula: C₅₂H₃₈N₄O₈
• Molecular Weight: 846.88
• Product Categories: Porphyrins
• Mol File: 22112-83-0.mol
• Article Data: 104

Chemical Properties

• Melting Point: 250 °C
• Appearance: /
• Density: 1.319±0.06 g/cm3(Predicted)
• CAS DataBase Reference: MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER(22112-83-0)
• EPA Substance Registry System: MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER(22112-83-0)

Safety Data

• Hazardous Substances Data: 22112-83-0(Hazardous Substances Data)

Usage

General Description

MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER is a chemical compound that belongs to the porphyrin family. It is a tetra-arylporphyrin with four carboxyphenyl groups attached to the central porphine ring. The tetramethyl ester modification indicates that each of the four carboxyphenyl groups has been esterified with a methyl group. MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER has potential applications in fluorescence imaging, photodynamic therapy, and catalysis due to its favorable photophysical properties and ability to form complexes with metal ions. Additionally, it has been studied for its potential as a photosensitizer for cancer therapy. The molecular structure and functional groups of MESO-TETRA(4-CARBOXYPHENYL)PORPHINE TETRAMETHYL ESTER make it a versatile and valuable compound for various research and industrial applications.

Upstream product

• 109-97-7 pyrrole 
• 1571-08-0 methyl 4-formylbenzoate 
• 112-54-9 Dodecanal 
• 167482-99-7 5-(4-carbomethoxyphenyl)dipyrromethane 
• 1312997-06-0 methyl 4-[hydroxyl(5-{hydroxyl[4-(methoxycarbonyl)phenyl]methyl}furan-2-yl)methyl]benzoate 
• 171824-87-6 2,5-[α-hydroxy-α-(p-tolyl)]methylfuran 
• 802294-64-0 propionic acid 
• 153364-63-7 4-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)benzaldehyde 
• 872-85-5 pyridine-4-carbaldehyde 
• 500-22-1 3-pyridinecarboxaldehyde 
• 121-33-5 vanillin 
• 3609-53-8 methyl 4-acetylbenzoate 
• 100-52-7 benzaldehyde 
• 13750-81-7 N-methyl-2-imidazolcarboxaldehyde 

Downstream Products

• 85857-14-3 5,10,15,20-tetrakis(p-chloromethylphenyl)porphyrin 
• 64466-25-7 [[μ-5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrinato(2-)]zinc(II)] 
• 64413-48-5 4,4′,4″,4?-(iron(III)porphine-5,10,15,20-tetrayl)-tetrakis(methyl benzoate) chloride 
• 19496-19-6 [5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrinato]cobalt(II) 
• 58188-48-0 [5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrinato]-nickel(II) 
• 853568-53-3 tetra methyl 4,4′,4″,4′″-(copperporphyrin-5,10,15,20-tetrayl)tetrabenzoate 
• 64413-48-5 [5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrinato]Fe(III) chloride 
• 19496-19-6 [5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrinato]-Co(II) 

Relevant articles and documents

Efficient routes to A3B-type meso -(4-Carboxyphenyl) porphyrin derivatives

A3B-type meso-(4-carboxyphenyl) porphyrins were prepared either by stepwise coupling of aniline substituents to meso-tetrakis(4-carboxyphenyl) porphyrin (TCPP) or by utilizing its partially protected trimethyl ester derivative. We demonstrate t

H2S-Activable MOF Nanoparticle Photosensitizer for Effective Photodynamic Therapy against Cancer with Controllable Singlet-Oxygen Release

Photodynamic therapy (PDT) has emerged as an important minimally invasive tumor treatment technology. The search for an effective photosensitizer to realize selective cancer treatment has become one of the major foci in recent developments of PDT technolo

Towards synthetic-porphyrin/monoclonal antibody conjugates

The synthesis of an unsymmetrically meso-aminoalkoxyphenyl-substituted porphyrin, and its conjugation to a monoclonal antibody (mAb), are described.

Triplet–Triplet Annihilation Upconversion in a MOF with Acceptor-Filled Channels

Photon upconversion has enjoyed increased interest in the last years due to its high potential for solar-energy harvesting and bioimaging. A challenge for triplet–triplet annihilation upconversion (TTA-UC) processes is to realize these features in solid materials without undesired phase segregation and detrimental dye aggregation. To achieve this, we combine a palladium porphyrin sensitizer and a 9,10-diphenylanthracene annihilator within a crystalline mesoporous metal–organic framework using an inverted design. In this modular TTA system, the framework walls constitute the fixed sensitizer, while caprylic acid coats the channels providing a solventlike environment for the mobile annihilator in the channels. The resulting solid material shows green-to-blue delayed upconverted emission with a luminescence lifetime of 373±5 μs, a threshold value of 329 mW cm?2 and a triplet–triplet energy transfer efficiency of 82 %. The versatile design allows straightforward changing of the acceptor amount and type.

Chlorin-Based Nanoscale Metal-Organic Framework Systemically Rejects Colorectal Cancers via Synergistic Photodynamic Therapy and Checkpoint Blockade Immunotherapy

Photodynamic therapy (PDT) can destroy local tumors and minimize normal tissue damage, but is ineffective at eliminating metastases. Checkpoint blockade immunotherapy has enjoyed recent success in the clinic, but only elicits limited rates of systemic ant

Boosting selective oxidation of cyclohexane over a metal-organic framework by hydrophobicity engineering of pore walls

A porphyrinic metal-organic framework (MOF), PCN-222(Fe), was found to exhibit sound activity and selectivity to cyclohexanone and cyclohexanol (known as KA oil) toward cyclohexane oxidation. Remarkably, hydrophobicity engineering of the MOF pore walls le

NMR Spectra of the Porphyrins Part 39. Paramagnetic Shifts in Cobalt(II) Porphyrins

A model of the paramagnetism in cobalt(II) porphyrin complexes has been developed which successfully calculates paramagnetic shifts for protons not affected by the contact term.The model utilizes a single large dipole positioned on the cobalt(II) atom, an

Dye-sensitized solar cells using supramolecular porphyrin arrays inspired by π-stacking structures of photosynthetic light-harvesting complexes

A slipped cofacial π-stacks of bis(4-carboxyphenyl)bis(1- methylimidazol-2-yl)porphyrinatomagnesium complex can be self-assembled onto TiO2 surface as a light-harvesting core. The porphyrin array allows a more favorable light-to-electricity conversion compared to the monomer analogue in dye-sensitized solar cells.

The effect of aromatic and non-aromatic ionic liquids on the optical nonlinearity responses of porphyrins

The effects of adding aromatic and nonaromatic ionic liquids (ILs) on third-order nonlinear optical (NLO) responses of 5,10,15,20-Tetrakis(4-methoxycarbonylphenyl) porphyrin (S1) and [5,10,15,20-Tetrakis(4-methoxycarbonylphenyl)-porphyrin]–Co (II) (S2) at

Straightforward synthesis of a porous chromium-based porphyrinic metal-organic framework for visible-light triggered selective aerobic oxidation of benzyl alcohol to benzaldehyde

Among MOFs, chromium-based metal–organic frameworks (Cr-MOFs) represent attractive scaffolds for variety of potential applications due to their high porosity and stability. Nevertheless, Cr-MOFs are not very common due to complicate synthesis. Cr-MOFs of large linkers are one clear example of synthetic limitations, since their preparation takes place by post-synthetic routes, commonly starting from Fe-MOFs as precursors. Hence, in this work, the direct synthesis of a phorphyrinic chromium-based MOF, Cr-PCN-600 (PCN stands for Porous Coordination Network) under solvothermal conditions is reported. The resulting Cr-MOF exhibits high surface area, permanent porosity, and broad light absorption wavelength range. Interestingly, this Cr-MOF is a highly effective heterogeneous photocatalyst for the selective aerobic oxidation of benzyl alcohol to benzaldehyde under visible light irradiation without any additive. Importantly, the Cr-MOF showed good recyclability maintaining its activity for three runs. The present results lay the foundation for both synthesis and applications of Cr-MOFs as robust photocatalysts in advanced organic transformations. Notably, quenching studies confirmed the generation of superoxide radical anion (O2[rad]?) and singlet oxygen (1O2) (mostly) as reactive species under the reaction conditions.