2-nitro-benzenesulfenic acid methyl ester

Base Information

• Chemical Name: 2-nitro-benzenesulfenic acid methyl ester
• CAS No.: 15666-75-8
• Molecular Formula: C₇H₇NO₃S
• Molecular Weight: 185.203
• Mol file: 15666-75-8.mol

Synonyms:2-nitro-benzenesulfenic acid methyl ester

Chemical Property of 2-nitro-benzenesulfenic acid methyl ester

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 2-nitro-benzenesulfenic acid methyl ester

There total 21 articles about 2-nitro-benzenesulfenic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.2%

4-[(2-nitrophenyl)sulfanyl]morpholine (7257-62-7) → 2-nitro-benzenesulfenic acid methyl ester (15666-75-8) + 2,4-bis(o-nitrophenylthio)-5,6-dihydro-2H-1,4-oxazinium perchlorate

Guidance literature:

With sodium perchlorate; In methanol; Ambient temperature;

DOI:10.1248/cpb.31.4530

Reference yield: 60.0%

methanol (67-56-1) + N,N-dimethyl-o-nitrobenzenesulphenamide (24398-41-2) → 2-nitro-benzenesulfenic acid methyl ester (15666-75-8)

Guidance literature:

trifluorormethanesulfonic acid; In diethyl ether; at 25 ℃; for 6h;

DOI:10.1021/jo00038a013

Reference yield: 60.0%

methanol (67-56-1) + 4-[(2-nitrophenyl)sulfanyl]morpholine (7257-62-7) → 2-nitro-benzenesulfenic acid methyl ester (15666-75-8)

Guidance literature:

trifluorormethanesulfonic acid; In acetonitrile; at 25 ℃; for 6h; Rate constant; Mechanism;

DOI:10.1021/jo00038a013

upstream raw materials:

methanol

(2-nitro-phenyl)-selenocyanato-sulfane

sodium methylate

2-nitrobenzenesulfenyl chloride

Downstream raw materials:

N-(2-nitro-benzenesulfenyl)-acetamidine

(2-Methoxy-1,1,2-trimethylpropyl)-2-nitro-phenyl-sulfid

2,5-Dimethylphenyl-2-nitrophenyl-sulfid

4-methoxyphenyl-2-nitrophenylsulfide