(+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triethylsilane

Base Information

Chemical Name:(+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triethylsilane
CAS No.:951133-51-0
Molecular Formula:C₂₃H₃₈O₂SSi
Molecular Weight:406.705
Hs Code.:

Synonyms:(+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triethylsilane

Suppliers and Price of (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triethylsilane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triethylsilane

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triethylsilane

There total 1 articles about (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 951133-45-2
(+)-(5S,S(S))-(4E)-4-(p-tolylsulfinyl)deca-1,3-dien-5-ol

: 994-30-9
triethylsilyl chloride

: 951133-51-0
(+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triethylsilane

Guidance literature:: With dmap; triethylamine; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 16h; Inert atmosphere;
DOI:10.1021/jo801803m

Reference yield: 35.0%

: 951133-51-0
(+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triethylsilane

: 951133-77-0
(-)-(5S)-(4E)-4-(p-tolylsulfonyl)deca-1,3-dien-5-ol

: 951133-79-2
(2R,5S)-5-pentyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-methanol

: 951133-63-4
(2S,5S)-5-pentyl-4-(p-tolylsulfonyl)-2,5-dihydrofuran-2-methanol

Guidance literature:: (+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triethylsilane; With (-)-chloro((1R,2R)-4,4',6,6'-tetra-tert-butyl-2,2'-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato)manganese(III); ammonium acetate; dihydrogen peroxide; In methanol; dichloromethane; at 0 - 4 ℃; for 48h; Inert atmosphere;

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 - 20 ℃; for 17h; optical yield given as %de; Further stages; Inert atmosphere;
DOI:10.1021/jo801803m

Reference yield:

: 951133-51-0
(+)-(5S,S(S))-(2E)-[4-(p-tolylsulfinyl)deca-1,3-dien-5-yloxy]triethylsilane

: 1092556-32-5
C₂₃H₃₈O₃SSi

: 1092556-90-5
C₂₃H₃₈O₄SSi

: 1092556-37-0
C₂₃H₃₈O₄SSi

Guidance literature:: With (-)-chloro((1R,2R)-4,4',6,6'-tetra-tert-butyl-2,2'-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato)manganese(III); ammonium acetate; dihydrogen peroxide; In methanol; dichloromethane; at 0 - 4 ℃; for 48h; optical yield given as %de; Inert atmosphere;
DOI:10.1021/jo801803m