1-<(Benzoyloxy)methyl>-1-<2-(benzoyloxy)-3-hydroxy-prop-1-yl>-4-methyl-2,5-cyclohexadiene

Base Information

Chemical Name:1-<(Benzoyloxy)methyl>-1-<2-(benzoyloxy)-3-hydroxy-prop-1-yl>-4-methyl-2,5-cyclohexadiene
CAS No.:75233-45-3
Molecular Formula:C₂₅H₂₆O₅
Molecular Weight:406.478
Hs Code.:

Synonyms:1-<(Benzoyloxy)methyl>-1-<2-(benzoyloxy)-3-hydroxy-prop-1-yl>-4-methyl-2,5-cyclohexadiene

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Chemical Property of 1-<(Benzoyloxy)methyl>-1-<2-(benzoyloxy)-3-hydroxy-prop-1-yl>-4-methyl-2,5-cyclohexadiene

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Technology Process of 1-<(Benzoyloxy)methyl>-1-<2-(benzoyloxy)-3-hydroxy-prop-1-yl>-4-methyl-2,5-cyclohexadiene

There total 5 articles about 1-<(Benzoyloxy)methyl>-1-<2-(benzoyloxy)-3-hydroxy-prop-1-yl>-4-methyl-2,5-cyclohexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 75233-56-6
1-<(Benzoyloxy)methyl>-1-<2-(benzoyloxy)-4,6,9-trioxodec-1-yl>-4-methyl-2,5-cyclohexadiene

: 75233-45-3
1-<(Benzoyloxy)methyl>-1-<2-(benzoyloxy)-3-hydroxy-prop-1-yl>-4-methyl-2,5-cyclohexadiene

Guidance literature:: With titanium tetrachloride; In hexane; dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1021/jo01312a003

Reference yield:

: 20646-36-0
4-methylcyclohexa-2,5-diene-1-carboxylic acid

: 75233-45-3
1-<(Benzoyloxy)methyl>-1-<2-(benzoyloxy)-3-hydroxy-prop-1-yl>-4-methyl-2,5-cyclohexadiene

Guidance literature:: Multi-step reaction with 5 steps

1: boron trifluoride etherate / 24 h / Heating

2: 1) 2,2,6,6-tetramethylpiperidine, n-butyllithium / 1) THF, hexane, 0 deg C, 15 min; 2) THF, -78 deg C; room temp., 2 h

3: 74 percent / LiAlH₄ / diethyl ether / 0.5 h / 0 °C

4: 87 percent / triethylamine / CH₂Cl₂ / 24 h / Heating

5: 90 percent / TiCl₄ / CH₂Cl₂; hexane / 0.5 h / 0 °C

With 2,2,6,6-tetramethyl-piperidine; lithium aluminium tetrahydride; n-butyllithium; boron trifluoride diethyl etherate; titanium tetrachloride; triethylamine; In diethyl ether; hexane; dichloromethane;
DOI:10.1021/jo01312a003

Reference yield:

: 75233-44-2
methyl 4-methylcyclohexa-2,5-diene-1-carboxylate

: 75233-45-3
1-<(Benzoyloxy)methyl>-1-<2-(benzoyloxy)-3-hydroxy-prop-1-yl>-4-methyl-2,5-cyclohexadiene

Guidance literature:: Multi-step reaction with 4 steps

1: 1) 2,2,6,6-tetramethylpiperidine, n-butyllithium / 1) THF, hexane, 0 deg C, 15 min; 2) THF, -78 deg C; room temp., 2 h

2: 74 percent / LiAlH₄ / diethyl ether / 0.5 h / 0 °C

3: 87 percent / triethylamine / CH₂Cl₂ / 24 h / Heating

4: 90 percent / TiCl₄ / CH₂Cl₂; hexane / 0.5 h / 0 °C

With 2,2,6,6-tetramethyl-piperidine; lithium aluminium tetrahydride; n-butyllithium; titanium tetrachloride; triethylamine; In diethyl ether; hexane; dichloromethane;
DOI:10.1021/jo01312a003