{iridium(I)(cyclo-octa-1,5-diene)(benzonitrile)(PPh₃)}ClO₄

Base Information

• Chemical Name: {iridium(I)(cyclo-octa-1,5-diene)(benzonitrile)(PPh₃)}ClO₄
• CAS No.: 134067-26-8
• Molecular Formula: C₃₃H₃₂IrNP*ClO₄
• Molecular Weight: 765.268
• Mol file: 134067-26-8.mol

Synonyms:{iridium(I)(cyclo-octa-1,5-diene)(benzonitrile)(PPh₃)}ClO₄

Chemical Property of {iridium(I)(cyclo-octa-1,5-diene)(benzonitrile)(PPh₃)}ClO₄

Chemical Property:

Purity/Quality:

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Technology Process of {iridium(I)(cyclo-octa-1,5-diene)(benzonitrile)(PPh₃)}ClO₄

There total 1 articles about {iridium(I)(cyclo-octa-1,5-diene)(benzonitrile)(PPh₃)}ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

IrCl(η-cyclo-octa-1,5-diene)(triphenylphosphine) (12115-50-3) + silver perchlorate + benzonitrile (100-47-0) → {iridium(I)(cyclo-octa-1,5-diene)(benzonitrile)(PPh3)}ClO4 (134067-26-8)

Guidance literature:

In dichloromethane; byproducts: AgCl; under nitrogen at room temp.; stirring for 30min;; addn. of hexane; filtrating of AgCl; elem. anal.;;

DOI:10.1039/DT9910000443

Reference yield: 85.0%

{iridium(I)(cyclo-octa-1,5-diene)(benzonitrile)(PPh3)}ClO4 (134067-26-8) → {IrH2(cycloocta-1,5-diene)(PPh3)(PhCN)}ClO4

Guidance literature:

With H₂; In dichloromethane; stirred under atm. pressure of H2 at -78°C for 1 h then addn. of cold hexane; filtration at -78°C, washed with cold hexane, dried in vac.;

upstream raw materials:

IrCl(η-cyclo-octa-1,5-diene)(triphenylphosphine)

benzonitrile

Refernces