Guanidine nitrate

Base Information

• Chemical Name: Guanidine nitrate
• CAS No.: 506-93-4
• Deprecated CAS: 24011-90-3,6609-93-4,2733504-07-7,52470-25-4
• Molecular Formula: CH6N4O3
• Molecular Weight: 122.084
• Hs Code.: 29252000
• European Community (EC) Number: 208-060-1
• ICSC Number: 0561
• NSC Number: 7295
• UN Number: 1467
• UNII: B542239A4E
• DSSTox Substance ID: DTXSID3027164
• Wikipedia: Guanidine nitrate
• Wikidata: Q411523
• Mol file: 506-93-4.mol

Synonyms:Guanidine,mononitrate (8CI,9CI);Guanidinium nitrate;NSC 7295;

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Chemical Property of Guanidine nitrate

Chemical Property:

• Appearance/Colour: solid
• Vapor Pressure: 0Pa at 25℃
• Melting Point: 213-215 °C(lit.)
• Refractive Index: 1.4164 (estimate)
• Boiling Point: 132.9 °C at 760 mmHg
• PKA: 10.2[at 20 ℃]
• Flash Point: 34.2 °C
• PSA: 141.94000
• Density: 1.44 g/cm³
• LogP: 0.51440
• Storage Temp.: Store below +30°C.
• Solubility.: water: soluble50mg/mL, clear to very slightly hazy, colorless
• Water Solubility.: 130 g/L (20 ºC)
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 122.04399007
• Heavy Atom Count: 8
• Complexity: 51
• Transport DOT Label: Oxidizer

Purity/Quality:

Safty Information:

• Pictogram(s): O,Xi,Xn
• Hazard Codes: O,Xn,Xi
• Statements: 8-22-36/37/38-5
• Safety Statements: 17-26-36-15

MSDS Files:

Useful:

• Chemical Classes: Nitrogen Compounds -> Nitrates and Nitrites
• Canonical SMILES: C(=N)(N)N.[N+](=O)(O)[O-]
• Inhalation Risk: A nuisance-causing concentration of airborne particles can be reached quickly when dispersed, especially if powdered.
• Effects of Short Term Exposure: The substance is severely irritating to the eyes and skin.
• Uses: Guanidine nitrate is the salt formed from guanidine and nitric acid and has been used as a high energy fuel used in gas generators and propellant applications. Guanidine nitrate has been used:in ammonium nitrate explosive formulations and in various propellant applications including triple-base gun propellantsto examine the vapor signatures of the nitrate salts of guanidine by isothermal thermogravimetric method

Technology Process of Guanidine nitrate

There total 15 articles about Guanidine nitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-Cyanoguanidine (127099-85-8,780722-26-1,461-58-5) → guanidine nitrate (506-93-4)

Guidance literature:

With ammonium nitrate; at 180 - 200 ℃; Darstellung;

Reference yield:

→ guanidine nitrate (506-93-4)

Guidance literature:

With ammonium nitrate; at 90 - 100 ℃;

Reference yield:

ammonium thiocyanate (1147550-11-5) → guanidine nitrate (506-93-4)

Guidance literature:

With ammonia; und folgendes Erhitzen mit 1 Mol Bleinitrat auf 120grad in geschlossenen Gefaessen;

upstream raw materials:

guanidinium thiocyanate

ammonium thiocyanate

sodium cyanamide

calcium cyanamide

Downstream raw materials:

2-Amino-5-ethylpyrimidin

4,5-dimethylpyrimidin-2-amine

4-methyl-5,6,7,8-tetrahydro-quinazolin-2-ylamine

nitroguanidine

Refernces

• 1、 Smith,Sabetta,Steinbach. "-". . p. 1127,1128. Retrieved 1931.
• 2、 -. "Production process of a guanidine nitrate". Paragraph 0020; 0021. . Retrieved 2017/03/08.
• 3、 Wandlowski, Thomas,Jameson, Geoffrey B.,Levie, Robert de. "Two-Dimensional Condensation of Guanidinium Nitrate at the Mercury-Water Interface". . p. 10119 - 10126. Retrieved 2007/10/02.