4,4′-bis[(4-nitrophenyl)amine]-4″-methoxytriphenylamine

Base Information

• Chemical Name: 4,4′-bis[(4-nitrophenyl)amine]-4″-methoxytriphenylamine
• CAS No.: 1350929-64-4
• Molecular Formula: C₃₁H₂₅N₅O₅
• Molecular Weight: 547.57
• Mol file: 1350929-64-4.mol

Synonyms:4,4′-bis[(4-nitrophenyl)amine]-4″-methoxytriphenylamine

Chemical Property of 4,4′-bis[(4-nitrophenyl)amine]-4″-methoxytriphenylamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4′-bis[(4-nitrophenyl)amine]-4″-methoxytriphenylamine

There total 4 articles about 4,4′-bis[(4-nitrophenyl)amine]-4″-methoxytriphenylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

4-Fluoronitrobenzene (350-46-9,178603-76-4) + 4,4'?diamino?4''?methoxytriphenylamine (134248-82-1) → 4,4′-bis[(4-nitrophenyl)amine]-4″-methoxytriphenylamine (1350929-64-4)

Guidance literature:

With triethylamine; In dimethyl sulfoxide;

DOI:10.1021/ma202128e

Reference yield:

4-Fluoronitrobenzene (350-46-9,178603-76-4) → 4,4′-bis[(4-nitrophenyl)amine]-4″-methoxytriphenylamine (1350929-64-4)

Guidance literature:

Multi-step reaction with 3 steps

1: cesium fluoride / dimethyl sulfoxide / 12 h / 150 °C / Inert atmosphere

2: palladium 10% on activated carbon; hydrazine hydrate / ethanol; water / 10 h / 75 °C

3: triethylamine / dimethyl sulfoxide / 72 h / 120 °C / Inert atmosphere

With palladium 10% on activated carbon; hydrazine hydrate; triethylamine; cesium fluoride; In ethanol; water; dimethyl sulfoxide;

Reference yield:

4,4'?dinitro?4''?methoxytriphenylamine → 4,4′-bis[(4-nitrophenyl)amine]-4″-methoxytriphenylamine (1350929-64-4)

Guidance literature:

Multi-step reaction with 2 steps

1: palladium 10% on activated carbon; hydrazine hydrate / ethanol; water / 10 h / 75 °C

2: triethylamine / dimethyl sulfoxide / 72 h / 120 °C / Inert atmosphere

With palladium 10% on activated carbon; hydrazine hydrate; triethylamine; In ethanol; water; dimethyl sulfoxide;

upstream raw materials:

4-Fluoronitrobenzene

4,4'?diamino?4''?methoxytriphenylamine

4-methoxy-aniline

Downstream raw materials:

4,4'-bis[(4-aminophenyl)amino]-4''-methoxytriphenylamine