RhH(octaethylporphyrin)

Base Information

• Chemical Name: RhH(octaethylporphyrin)
• CAS No.: 63372-77-0
• Molecular Formula: C₃₆H₄₅N₄Rh
• Molecular Weight: 636.686
• Mol file: 63372-77-0.mol

Synonyms:RhH(octaethylporphyrin)

Chemical Property of RhH(octaethylporphyrin)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RhH(octaethylporphyrin)

There total 4 articles about RhH(octaethylporphyrin) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

octaethylporphyrinatorhodium(II) dimer (63439-10-1) + ethylbenzene (100-41-4,27536-89-6) → (octaethylporphyrinato)(hydrido)rhodium(II) (63372-77-0) + ((C2H5)8C20H4N4)Rh(CH2CH2C6H5) (96502-53-3) + ((C2H5)8C20H4N4)Rh(CH(C6H5)CH3) (99248-50-7)

Guidance literature:

In not given; Schlenk techniques, thermal react. of Rh-complex with ethylbenzene in sealed tube in the dark for 24 h at 109°C;

DOI:10.1021/ja00312a023

Reference yield: 36.0%

octaethylporphyrinatorhodium(II) dimer (63439-10-1) + phenylpropane (103-65-1) → ((C2H5)8C20H4N4)Rh(CH(C6H5)CH2CH3) (99248-51-8) + ((C2H5)8C20H4N4)Rh(CH2CH2CH2C6H5) (99248-53-0) + (octaethylporphyrinato)(hydrido)rhodium(II) (63372-77-0) + ((C2H5)8C20H4N4)Rh(CH(CH3)CH2C6H5) (99248-52-9)

Guidance literature:

In not given; Schlenk techniques, thermal react. of Rh-complex with n-PrPh in sealed tube in the dark for 24 h at 109°C;

DOI:10.1021/ja00312a023

Reference yield: 12.5%

octaethylporphyrinatorhodium(II) dimer (63439-10-1) + ethylbenzene (100-41-4,27536-89-6) → (octaethylporphyrinato)(hydrido)rhodium(II) (63372-77-0) + ((C2H5)8C20H4N4)Rh(CH(C6H5)CH3) (99248-50-7)

Guidance literature:

In not given; Schlenk techniques, thermal react. of Rh-complex with ethylbenzene in sealed tube in the dark for 1 h at 109°C;

DOI:10.1021/ja00312a023

upstream raw materials:

octaethylporphyrinatorhodium(II) dimer

ethylbenzene

phenylpropane

acetophenone

Downstream raw materials:

((C₂H₅)8C₂₀H₄N₄)Rh(CH(CH₃)CH₂C₆H₅)

((C₂H₅)8C₂₀H₄N₄)Rh(CH₂CH₂C₆H₅)

((C₂H₅)8C₂₀H₄N₄)Rh(CH₂CH₂CH₂C₆H₅)

((C₂H₅)8C₂₀H₄N₄)Rh(CH(C₆H₅)CH₃)