octaethylporphyrinatorhodium(II) dimer

Base Information

Chemical Name:octaethylporphyrinatorhodium(II) dimer
CAS No.:63439-10-1
Molecular Formula:C₇₂H₈₈N₈Rh₂
Molecular Weight:1271.36
Hs Code.:

Synonyms:octaethylporphyrinatorhodium(II) dimer

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Chemical Property of octaethylporphyrinatorhodium(II) dimer

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Technology Process of octaethylporphyrinatorhodium(II) dimer

There total 1 articles about octaethylporphyrinatorhodium(II) dimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 63372-77-0
(octaethylporphyrinato)(hydrido)rhodium(II)

: 63439-10-1
octaethylporphyrinatorhodium(II) dimer

: 1333-74-0
hydrogen

Guidance literature:: In benzene; (OEP)Rh(H) dissolved in 15-20 ml of degassed benzene, stirred for 1 week under vacuum with periodic freeze-pump-thaw cycles to remove evolved hydrogen;; benzene is stripped off on the vacuum line;;
DOI:10.1021/ja00226a022

Reference yield: 65.0%

: 63439-10-1
octaethylporphyrinatorhodium(II) dimer

: 789-25-3
HSiPh₃

: 159626-69-4
(2,3,7,8,12,13,17,18=octaethylporphyrinato)Rh(SiPh₃)

Guidance literature:: In benzene; Ar-atmosphere; stirring (room temp., 12 h); evapn. (reduced pressure), chromy. (SiO2, C6H6 / hexane = 1 : 2), recrystn. (CHCl3 / hexane);
DOI:10.1021/om00001a049

Reference yield: 50.0%

: 63439-10-1
octaethylporphyrinatorhodium(II) dimer

: 108-38-3,104809-90-7
m-xylene

: ((C₂H₅)8C₂₀H₄N₄)RhCH₂C₆H₄CH₃

Guidance literature:: In not given; byproducts: H2; Schlenk techniques, thermal react. of Rh-complex with m-xylene in sealed tube in the dark for 24 h at 125°C;
DOI:10.1021/ja00312a023