Ethylene glycol diglycidyl ether

Base Information

• Chemical Name: Ethylene glycol diglycidyl ether
• CAS No.: 2224-15-9
• Deprecated CAS: 156477-59-7,162786-26-7,186355-00-0,2102862-81-5,186355-00-0
• Molecular Formula: C8H14O4
• Molecular Weight: 174.197
• Hs Code.: 29109000
• European Community (EC) Number: 218-746-2,639-687-2
• NSC Number: 54740
• UNII: 5R860RS597
• DSSTox Substance ID: DTXSID4044876
• Nikkaji Number: J116.203I
• Wikidata: Q27262769
• ChEMBL ID: CHEMBL3182506
• Mol file: 2224-15-9.mol

Synonyms:bis(1,2-epoxypropylether)ethanediol

Chemical Property of Ethylene glycol diglycidyl ether

Chemical Property:

• Appearance/Colour: Clear yellow liquid
• Vapor Pressure: 0.172mmHg at 25°C
• Refractive Index: n20/D 1.463(lit.)
• Boiling Point: 266.774 °C at 760 mmHg
• Flash Point: 123.633 °C
• PSA: 43.52000
• Density: 1.178 g/cm³
• LogP: -0.18280
• Storage Temp.: 2-8°C
• XLogP3: -0.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 7
• Exact Mass: 174.08920892
• Heavy Atom Count: 12
• Complexity: 123

Purity/Quality:

99% ^*data from raw suppliers

Ethylene Glycol Diglycidyl Ether (so called) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Plastics & Rubber -> Polymers
• Canonical SMILES: C1C(O1)COCCOCC2CO2
• Uses: Ethylene Glycol Diglycidyl Ether is commonly added to asorbants because of it high carbon dioxide absorbing capacity.

Technology Process of Ethylene glycol diglycidyl ether

There total 2 articles about Ethylene glycol diglycidyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

ethylene glycol (107-21-1) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → ethylene glycol diglycidyl ether (2224-15-9,29317-04-2,64859-56-9)

Guidance literature:

With tetrabutyl-ammonium chloride; water; sodium hydroxide; at 40 ℃; for 0.75h;

DOI:10.1016/j.ab.2020.113693

Reference yield:

1,10-Dichloro-4,7-dioxa-2,9-decanediol (13078-45-0) → ethylene glycol diglycidyl ether (2224-15-9,29317-04-2,64859-56-9)

Guidance literature:

With sodium hydroxide;

Reference yield: 80.0%

ethylene glycol diglycidyl ether (2224-15-9,29317-04-2,64859-56-9) + N,N'-dibenzyl-1,3-diaminopropane (10239-34-6) → 8,11-dibenzyl-1,4-dioxa-8,11-diaza-cyclotetradecane-6,13-diol

Guidance literature:

With sodium hydride; In water; Heating;

DOI:10.1016/S0040-4039(99)02219-4

upstream raw materials:

ethylene glycol

epichlorohydrin

1,10-Dichloro-4,7-dioxa-2,9-decanediol

Downstream raw materials:

1,10-Dichloro-4,7-dioxa-2,9-decanediol

5,5'-(5,12-dihydroxy-2,15-dioxo-7,10-dioxa-3,14-diazahexadecane-3,14-diyl)bis(N₁,N₁,N₃,N₃-tetrakis(2-hydroxyethyl)-2,4,6-triiodoisophthalamide)

5,5'-(5,12-dihydroxy-2,15-dioxo-7,10-dioxa-3,14-diazahexadecane-3,14-diyl)bis(N₁,N₃-bis(2,3-dihydroxypropyl)-2,4,6-triiodo-N₁,N₃-dimethylisophthalamide)

C₃₄H₃₄O₈

Refernces

• 1、 Abbasi, Hassan,Pourrostam-Ravadanaq, Pariya,Safa, Kazem D.. "Study of imidazole performance as pseudo-affinity ligand in the purification of IgG from bovine milk". . . Retrieved 2020.
• 2、 -. "Polyoxyethylene ether carboxylic acid dimeric surfactant type drag reducer as well as preparation method and application thereof". Paragraph 0087; 0090-0091; 0096; 0099-0100; 0105; 0108-0109. . Retrieved 2019/09/13.