Ru(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)Cl₃

Base Information

• Chemical Name: Ru(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)Cl₃
• CAS No.: 259251-59-7
• Molecular Formula: C₂₅H₁₉Cl₃N₃ORu
• Molecular Weight: 584.874
• Mol file: 259251-59-7.mol

Synonyms:Ru(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)Cl₃

Chemical Property of Ru(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)Cl₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)Cl₃

There total 1 articles about Ru(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)Cl₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

ruthenium(III) chloride trihydrate (14898-67-0) + 2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline (201403-32-9) → Ru(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)Cl3 (259251-59-7)

Guidance literature:

In ethanol; to abs. EtOH were added RuCl3*3H2O and ligand, mixt. heated at reflux for 3 h with vigorous stirring, mixt. was cooled to room temp.; ppt. was collected by vac. filtration, washed with abs. EtOH, followed by Et2O, dried under vac.;

DOI:10.1002/(sici)1099-0682(200001)2000:1<113::aid-ejic113>3.0.co;2-9

Reference yield: 87.0%

potassium hexafluorophosphate (17084-13-8) + Ru(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)Cl3 (259251-59-7) + 2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline (201403-32-9) → bis(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)ruthenium(II) dihexafluorophosphate

Guidance literature:

With N-ethylmorpholine; In water; acetic acid; suspn. of Ru-complex and ligand in glacial acetic acid with 2-3 drops ofN-ethylmorpholine was refluxed under Ar for 3 h; solvent removed under reduced pressure, solid redissolved in MeOH, filtered, aq. soln. of KPF6 was added, silica gel chromy., eluted with CH2Cl2/CH3OH; elem. anal.;

DOI:10.1002/(sici)1099-0682(200001)2000:1<113::aid-ejic113>3.0.co;2-9

Reference yield: 41.0%

potassium hexafluorophosphate (17084-13-8) + Ru(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)Cl3 (259251-59-7) + 2,9-bis-(4-methylphenyl)-1,10-phenanthroline (116287-98-0) → (2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)(2,9-bis(p-tolyl)-1,10-phenanthroline)ruthenium(II) hexafluorophosphate (259251-55-3)

Guidance literature:

With N-ethylmorpholine; In water; acetic acid; suspn. of Ru-complex and ligand in glacial acetic acid with 2-3 drops ofN-ethylmorpholine was refluxed under Ar for 3 h; solvent removed under reduced pressure, solid redissolved in MeOH, filtered, aq. soln. of KPF6 was added, silica gel chromy., eluted with CH2Cl2/CH3OH; elem. anal.;

DOI:10.1002/(sici)1099-0682(200001)2000:1<113::aid-ejic113>3.0.co;2-9

upstream raw materials:

ruthenium(III) chloride trihydrate

2-(p-methoxyphenyl)-9-(5'-methylpyridin-2'-yl)-1,10-phenanthroline

Downstream raw materials:

(2-p-anisyl-9-(4-methyl-2-pyridyl)-1,10-phenanthroline)(2,9-bis(p-tolyl)-1,10-phenanthroline)ruthenium(II) hexafluorophosphate