2,6-bis(diphenylphosphinomethyl)phenylbromonickel

Base Information

Chemical Name:2,6-bis(diphenylphosphinomethyl)phenylbromonickel
CAS No.:615569-94-3
Molecular Formula:C₃₂H₂₇BrNiP₂
Molecular Weight:612.108
Hs Code.:

Synonyms:2,6-bis(diphenylphosphinomethyl)phenylbromonickel

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Chemical Property of 2,6-bis(diphenylphosphinomethyl)phenylbromonickel

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Technology Process of 2,6-bis(diphenylphosphinomethyl)phenylbromonickel

There total 2 articles about 2,6-bis(diphenylphosphinomethyl)phenylbromonickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 13463-39-3,71564-36-8
tetracarbonyl nickel

: 235104-95-7
2,6-bis[(diphenylphosphanyl)methyl]bromobenzene

: 615569-94-3
2,6-bis(diphenylphosphinomethyl)phenylbromonickel

Guidance literature:: In toluene; byproducts: CO; Ni(CO)4 was condenced to frozen soln. of diphosphine in toluene, the mixt. was allowed to warm up to ambient temp., after the end of gas alimination soln. was heated in water bath (80°C); cooled, filtered, recrystd. from THF; elem. anal.;
DOI:10.1039/b407972h

Reference yield: 39.0%

: nickel(II) bromide trihydrate

: 89756-88-7
1,3-bis(diphenylphosphinomethyl)benzene

: 615569-94-3
(2,6-bis(diphenylphosphinomethyl)phenyl)bromonickel

Guidance literature:: nickel(II) bromide trihydrate; 1,3-bis(diphenylphosphinomethyl)benzene; In ethanol; at 60 ℃; for 3h;

With N-ethyl-N,N-diisopropylamine; In ethanol; for 0.5h; Reflux;
DOI:10.1021/acs.organomet.1c00033