zinc 5,15-bis-(3,5-bis-octyloxy-phenyl)-10,20-bis-ethynyl-porphyrin dimer

Base Information

Chemical Name:zinc 5,15-bis-(3,5-bis-octyloxy-phenyl)-10,20-bis-ethynyl-porphyrin dimer
CAS No.:937026-98-7
Molecular Formula:C₁₃₆H₁₆₆N₈O₈Zn₂
Molecular Weight:2171.64
Hs Code.:

Synonyms:zinc 5,15-bis-(3,5-bis-octyloxy-phenyl)-10,20-bis-ethynyl-porphyrin dimer

Suppliers and Price of zinc 5,15-bis-(3,5-bis-octyloxy-phenyl)-10,20-bis-ethynyl-porphyrin dimer

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of zinc 5,15-bis-(3,5-bis-octyloxy-phenyl)-10,20-bis-ethynyl-porphyrin dimer

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of zinc 5,15-bis-(3,5-bis-octyloxy-phenyl)-10,20-bis-ethynyl-porphyrin dimer

There total 2 articles about zinc 5,15-bis-(3,5-bis-octyloxy-phenyl)-10,20-bis-ethynyl-porphyrin dimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 917596-91-9
[(zinc(C₂₀H₈N₄(3,5-dioctyloxy)phenyl)2)2(CC)2(CCSi(C₆H₁₃)3)2]

: 937026-98-7
C₁₃₆H₁₆₆N₈O₈Zn₂

Guidance literature:: [(zinc(C₂₀H₈N₄(3,5-dioctyloxy)phenyl)2)2(CC)2(CCSi(C₆H₁₃)3)2]; With tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; for 0.25h;

With calcium chloride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja802281c

Reference yield:

: 917596-91-9
zinc 5,15-bis-(3,5-bis-octyloxy-phenyl)-10,20-bis-trihexylsilanylethynyl-porphyrin dimer

: 937026-89-6
zinc 5,15-bis-(3,5-bis-octyloxy-phenyl)-10-ethynyl-20-trihexylsilanylethynyl-porphyrin dimer

: 937026-98-7
zinc 5,15-bis-(3,5-bis-octyloxy-phenyl)-10,20-bis-ethynyl-porphyrin dimer

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; chloroform; at 20 ℃; for 1.5h; Inert atmosphere;
DOI:10.1039/c4tc01120a

Reference yield: 33.0%

: 591215-23-5
hexakis[4-(4-pyridyl)phenyl]benzene

: 937026-98-7
zinc 5,15-bis-(3,5-bis-octyloxy-phenyl)-10,20-bis-ethynyl-porphyrin dimer

: [(zinc(N₄C₂₀H₈(C₆H₃(octyloxy)2)2)(CC)2)6C₆(C₆H₄C₅H₄N)6]

Guidance literature:: With air; I₂; catalysts: PdCl₂(PPh₃)2/CuI; In toluene; react. of (Zn(N4C20H8(C6H3(OC8H17)2)2)(CC)(CCH))2, C6(C6H4C5H4N)6, I2 and air oxidants, PdCl2(P(C6H5)2)2/CuI catalysts, further reagent; A.S. Batsanov, J.C. Collins, I.J.S. Fairlamb, J.P. Holland, J.A.K. Howard et al.J. Org. Chem. 2005, 70, 709-706;
DOI:10.1002/anie.200801188