(1S-exo)-2-bornyl 2,4-dinitrophenyl sulfide

Base Information

• Chemical Name: (1S-exo)-2-bornyl 2,4-dinitrophenyl sulfide
• CAS No.: 130592-83-5
• Molecular Formula: C₁₆H₂₀N₂O₄S
• Molecular Weight: 336.412
• Mol file: 130592-83-5.mol

Synonyms:(1S-exo)-2-bornyl 2,4-dinitrophenyl sulfide

Chemical Property of (1S-exo)-2-bornyl 2,4-dinitrophenyl sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1S-exo)-2-bornyl 2,4-dinitrophenyl sulfide

There total 4 articles about (1S-exo)-2-bornyl 2,4-dinitrophenyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

(1S,2S,4S)-1,7,7-trimethylbicyclo<2.2.1>heptane-2-thiol (5391-78-6,6704-56-9,34942-24-0,75044-78-9,126452-83-3,130695-53-3) + 1-chloro-2,4-dinitro-benzene (97-00-7) → (1S-exo)-2-bornyl 2,4-dinitrophenyl sulfide (130592-83-5)

Guidance literature:

With sodium hydroxide; In ethanol; 1a) 60 deg C, 10 min, 1b) 0 deg C, 18 h;

DOI:10.1055/s-1990-26948

Reference yield:

endo-borneol (464-45-9) → (1S-exo)-2-bornyl 2,4-dinitrophenyl sulfide (130592-83-5)

Guidance literature:

Multi-step reaction with 4 steps

1: 97 percent / pyridine / 24 h / Ambient temperature

2: 72 percent / propan-2-ol / 13 h / Heating

3: 85 percent / 0.4N NaOH / H₂O / Heating

4: 80 percent / NaOH / aq. ethanol / 1a) 60 deg C, 10 min, 1b) 0 deg C, 18 h

With pyridine; sodium hydroxide; In ethanol; water; isopropyl alcohol;

DOI:10.1055/s-1990-26948

Reference yield:

L-bornyl p-toluenesulfonate (20053-48-9) → (1S-exo)-2-bornyl 2,4-dinitrophenyl sulfide (130592-83-5)

Guidance literature:

Multi-step reaction with 3 steps

1: 72 percent / propan-2-ol / 13 h / Heating

2: 85 percent / 0.4N NaOH / H₂O / Heating

3: 80 percent / NaOH / aq. ethanol / 1a) 60 deg C, 10 min, 1b) 0 deg C, 18 h

With sodium hydroxide; In ethanol; water; isopropyl alcohol;

DOI:10.1055/s-1990-26948

upstream raw materials:

(1S,2S,4S)-1,7,7-trimethylbicyclo<2.2.1>heptane-2-thiol

1-chloro-2,4-dinitro-benzene

endo-borneol

L-bornyl p-toluenesulfonate

Downstream raw materials:

(1S-exo)-2-bornyl 2,4-dinitrophenyl sulfone