(((CH₃)2CH)3C₆H₂)Ge(C(CH₃)3)OC(C(C₆H₅)2)AsC₆H₂(C(CH₃)3)2C(CH₃)2CH₂CH

Base Information

• Chemical Name: (((CH₃)2CH)3C₆H₂)Ge(C(CH₃)3)OC(C(C₆H₅)2)AsC₆H₂(C(CH₃)3)2C(CH₃)2CH₂CH
• CAS No.: 1358751-33-3
• Molecular Formula: C₅₂H₇₁AsGeO
• Molecular Weight: 859.647
• Mol file: 1358751-33-3.mol

Synonyms:(((CH₃)2CH)3C₆H₂)Ge(C(CH₃)3)OC(C(C₆H₅)2)AsC₆H₂(C(CH₃)3)2C(CH₃)2CH₂CH

Chemical Property of (((CH₃)2CH)3C₆H₂)Ge(C(CH₃)3)OC(C(C₆H₅)2)AsC₆H₂(C(CH₃)3)2C(CH₃)2CH₂CH

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (((CH₃)2CH)3C₆H₂)Ge(C(CH₃)3)OC(C(C₆H₅)2)AsC₆H₂(C(CH₃)3)2C(CH₃)2CH₂CH

There total 3 articles about (((CH₃)2CH)3C₆H₂)Ge(C(CH₃)3)OC(C(C₆H₅)2)AsC₆H₂(C(CH₃)3)2C(CH₃)2CH₂CH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

1-(2,4,6-tri-tert-butylphenyl)-3-(2,4,6-triisopropylphenyl)-3-tert-butyl-1-arsa-3-germaallene (1266860-52-9) + diphenyl ketene (525-06-4) → (((CH3)2CH)3C6H2)Ge(C(CH3)3)OC(C(C6H5)2)AsC6H2(C(CH3)3)2C(CH3)2CH2CH (1358751-33-3)

Guidance literature:

In diethyl ether; under Ar; diphenylketene in Et2O added to soln. of Ge-As compd. in Et2O at -80°C; stirred at -80°C for 15 min; warmed to room temp.; solvent eliminated under vac.; replaced by pentane; filtered; filtrate concd.; crystd. at -20°C; elem. anal.;

DOI:10.1021/om200968x

Reference yield:

difluoro(2,4,6-triisopropylphenyl)(tert-butyl)germane (438201-92-4) → (((CH3)2CH)3C6H2)Ge(C(CH3)3)OC(C(C6H5)2)AsC6H2(C(CH3)3)2C(CH3)2CH2CH (1358751-33-3)

Guidance literature:

Multi-step reaction with 3 steps

1: n-BuLi / diethyl ether; hexane

2: tert-butyllithium / pentane; diethyl ether

3: diethyl ether

With n-BuLi; tert-butyllithium; In diethyl ether; hexane; pentane;

DOI:10.1021/om200968x

Reference yield:

1-(2,4,6-tri-tert-butylphenyl)-2-bromo-3-fluoro-3-(2,4,6-triisopropylphenyl)-3-tert-butyl-1-arsa-3-germapropene (1266860-54-1) → (((CH3)2CH)3C6H2)Ge(C(CH3)3)OC(C(C6H5)2)AsC6H2(C(CH3)3)2C(CH3)2CH2CH (1358751-33-3)

Guidance literature:

Multi-step reaction with 2 steps

1: tert-butyllithium / pentane; diethyl ether

2: diethyl ether

With tert-butyllithium; In diethyl ether; pentane;

DOI:10.1021/om200968x

upstream raw materials:

difluoro(2,4,6-triisopropylphenyl)(tert-butyl)germane

1-(2,4,6-tri-tert-butylphenyl)-3-(2,4,6-triisopropylphenyl)-3-tert-butyl-1-arsa-3-germaallene

diphenyl ketene

1-(2,4,6-tri-tert-butylphenyl)-2-bromo-3-fluoro-3-(2,4,6-triisopropylphenyl)-3-tert-butyl-1-arsa-3-germapropene