438201-92-4

Upstream product

• 438201-91-3 tert-butyl-2,4,6-triisopropylphenyl(dimethoxy)germane 
• 7664-39-3 hydrogen fluoride 
• 190080-50-3 trichloro(2,4,6-triisopropylphenyl)germane 
• 21524-34-5 2,4,6-triisopropyl-1-bromobenzene 

Downstream Products

• 438201-93-5 (2,4,6-triisopropylphenyl)(t-Bu)Ge(F)C(Cl)P(2,4,6-tri-tert-butylphenyl) 
• 438201-89-9 3-(2,4,6-triisopropylphenyl)-3-tert-butyl-1-(2,4,6-tri-tert-butylphenyl)germaphosphaallene 
• 438201-95-7 (C₃H₇)3C₆H₂GeOHC₄H₉CHP(C₄H₉)3C₆H₂ 
• 438201-97-9 (C₃H₇)3C₆H₂GeOC₄H₉C(C₆H₅)2CP(C₄H₉)3C₆H₂ 
• 1229608-24-5 (2,4,6-tri-tert-butylphenyl)P=C(H)Ge(t-Bu)(2,4,6-triisopropylphenyl)(OCH(=CH₂)C(H)=CH₂) 
• 1229608-23-4 (2,4,6-tri-tert-butylphenyl)P=CGe(t-Bu)(2,4,6-triisopropylphenyl)OC(Me)=C(H)CH₂ 
• 1229608-25-6 (2,4,6-tri-tert-butylphenyl)P=C(H)Ge(t-Bu)(2,4,6-triisopropylphenyl)(OCH(=CH₂)Ph 
• 1266860-54-1 1-(2,4,6-tri-tert-butylphenyl)-2-bromo-3-fluoro-3-(2,4,6-triisopropylphenyl)-3-tert-butyl-1-arsa-3-germapropene 
• 1358751-26-4 (((CH₃)2CH)3C₆H₂)Ge(C(CH₃)3)OC₁₄H₈OCAsC₆H₂(C(CH₃)3)3 
• 1358751-22-0 (((CH₃)2CH)3C₆H₂)Ge(C(CH₃)3)OC₁₃H₈CAsC₆H₂(C(CH₃)3)3 
• 1358751-33-3 (((CH₃)2CH)3C₆H₂)Ge(C(CH₃)3)OC(C(C₆H₅)2)AsC₆H₂(C(CH₃)3)2C(CH₃)2CH₂CH 
• 1358751-28-6 (((CH₃)2CH)3C₆H₂)Ge(C(CH₃)3)OC(C₆H₅)(COC₆H₅)CAsC₆H₂(C(CH₃)3)3 
• 1358751-31-1 (((CH₃)2CH)3C₆H₂)Ge(C(CH₃)3)OC(C₆H₅)C(C₆H₅)OCAsC₆H₂(C(CH₃)3)3 
• 1358751-20-8 (((CH₃)2CH)3C₆H₂)Ge(C(CH₃)3)SeCAsC₆H₂(C(CH₃)3)3 

Relevant academic research and scientific papers

The reactivity of phosphagermaallene Mes*P=C=Ge(t -Bu)tip toward aldehydes and ketones: An experimental and theoretical study

Phosphagermaallene Mes*P=C=Ge(t-Bu)Tip 1 (Tip = 2,4,6- triisopropylphenyl, Mes* = 2,4,6-tri-tert-butylphenyl) has been obtained by an improved synthesis in relation to the previously reported preparation starting from t-BuGeCl3. Very short Ge=C (1.761(2) A) and P=C (1.625(2) A) double bond lengths, trigonal planar geometry around the Ge atom, and GeCP bond angle of 166.57° are indicative of an heteroallenic structure for 1. Its reactions with crotonaldehyde and cinnamaldehyde lead to 1-oxa-2-germacyclobutanes by a [2 + 2] cycloaddition between the Ge=C and C=O double bonds; with methyl vinyl ketone, both a [2 + 4] cycloaddition between the Ge=C and the O=C-C=C moieties and an ene-reaction are observed leading to a 1-oxa-2-germacyclohex-5-ene and a germyl(butadienyl)ether, respectively. With acetophenone, an ene-reaction occurs to afford exclusively a germyl(vinyl)ether. DFT calculations have been performed to explain the regiochemistry observed.

The first stable 3,1-germaphosphaallene Tip(t-Bu)Ge=C=PAr

The first stable heteroallenic derivative with two heavy doubly-bonded Group 14 and 15 elements, the germaphosphaallene Tip(t-Bu)Ge=C=PAr 1 (Tip = 2,4,6-triisopropylphenyl, Ar = 2,4,6-tri-tert-butylphenyl), has been prepared in a nearly quantitative yield by dechlorofluorination of Tip(t-Bu)Ge(F)-C(C1)=PAr (obtained from ArP=CC12 and successive reaction with n-butyllithium and Tip(t-Bu)GeF2) with tert-butyllithium. 1 gives [2 + 2] cycloadducts by the Ge=C double bond with benzaldehyde, benzophenone and fluorenone to afford the corresponding germaoxetanes 11 - 13. 13 has been structurally characterized showing a long Ge-O bond (1.821(2) ?) and a slightly folded four-membered ring GeOCC (18.8° along C(1)Ge axis).