N,N-diphenyl-4'-(4-(2-phenyl-1H-benzo[d]imidazol-1-yl)phenyl)-[1,1'-binaphthalen]-4-amine

Base Information

Chemical Name:N,N-diphenyl-4'-(4-(2-phenyl-1H-benzo[d]imidazol-1-yl)phenyl)-[1,1'-binaphthalen]-4-amine
CAS No.:1599466-11-1
Molecular Formula:C₅₁H₃₅N₃
Molecular Weight:689.859
Hs Code.:

Synonyms:N,N-diphenyl-4'-(4-(2-phenyl-1H-benzo[d]imidazol-1-yl)phenyl)-[1,1'-binaphthalen]-4-amine

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Chemical Property of N,N-diphenyl-4'-(4-(2-phenyl-1H-benzo[d]imidazol-1-yl)phenyl)-[1,1'-binaphthalen]-4-amine

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Technology Process of N,N-diphenyl-4'-(4-(2-phenyl-1H-benzo[d]imidazol-1-yl)phenyl)-[1,1'-binaphthalen]-4-amine

There total 5 articles about N,N-diphenyl-4'-(4-(2-phenyl-1H-benzo[d]imidazol-1-yl)phenyl)-[1,1'-binaphthalen]-4-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 1169709-19-6
2-phenyl-1-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-1H-benzo[d]imidazole

: 1374559-53-1
4'-bromo-N,N-diphenyl-1,1'-binaphthyl-4-amine

: 1599466-11-1
N,N-diphenyl-4'-(4-(2-phenyl-1H-benzo[d]imidazol-1-yl)phenyl)-[1,1'-binaphthalen]-4-amine

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium fluoride; In N,N-dimethyl-formamide; at 120 ℃; for 12h; Inert atmosphere; Schlenk technique;
DOI:10.1016/j.tet.2014.03.017

Reference yield:

: 1493-27-2,127723-77-7
ortho-nitrofluorobenzene

: 1599466-11-1
N,N-diphenyl-4'-(4-(2-phenyl-1H-benzo[d]imidazol-1-yl)phenyl)-[1,1'-binaphthalen]-4-amine

Guidance literature:: Multi-step reaction with 5 steps

1: dimethyl sulfoxide / 48 h / 100 °C / Inert atmosphere; Schlenk technique

2: tin(II) chloride dihdyrate / ethanol / 3 h / Inert atmosphere; Reflux; Schlenk technique

3: 2-methoxy-ethanol / 12 h / Inert atmosphere; Schlenk technique; Reflux

4: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / 1,4-dioxane / 12 h / 80 °C / Inert atmosphere; Schlenk technique

5: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium fluoride / N,N-dimethyl-formamide / 12 h / 120 °C / Inert atmosphere; Schlenk technique

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium fluoride; tin(II) chloride dihdyrate; potassium acetate; In 1,4-dioxane; ethanol; 2-methoxy-ethanol; dimethyl sulfoxide; N,N-dimethyl-formamide; 4: |Miyaura Borylation Reaction / 5: |Suzuki Coupling;
DOI:10.1016/j.tet.2014.03.017

Reference yield:

: 106-40-1
4-bromo-aniline

: 1599466-11-1
N,N-diphenyl-4'-(4-(2-phenyl-1H-benzo[d]imidazol-1-yl)phenyl)-[1,1'-binaphthalen]-4-amine

Guidance literature:: Multi-step reaction with 5 steps

1: dimethyl sulfoxide / 48 h / 100 °C / Inert atmosphere; Schlenk technique

2: tin(II) chloride dihdyrate / ethanol / 3 h / Inert atmosphere; Reflux; Schlenk technique

3: 2-methoxy-ethanol / 12 h / Inert atmosphere; Schlenk technique; Reflux

4: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate / 1,4-dioxane / 12 h / 80 °C / Inert atmosphere; Schlenk technique

5: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium fluoride / N,N-dimethyl-formamide / 12 h / 120 °C / Inert atmosphere; Schlenk technique

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium fluoride; tin(II) chloride dihdyrate; potassium acetate; In 1,4-dioxane; ethanol; 2-methoxy-ethanol; dimethyl sulfoxide; N,N-dimethyl-formamide; 4: |Miyaura Borylation Reaction / 5: |Suzuki Coupling;
DOI:10.1016/j.tet.2014.03.017