ZnN₄C₂₀H₉(C₆H₃(C(CH₃)3)2)2C₆H₄CN

Base Information

• Chemical Name: ZnN₄C₂₀H₉(C₆H₃(C(CH₃)3)2)2C₆H₄CN
• CAS No.: 637765-01-6
• Molecular Formula: C₅₅H₅₅N₅Zn
• Molecular Weight: 851.465
• Mol file: 637765-01-6.mol

Synonyms:ZnN₄C₂₀H₉(C₆H₃(C(CH₃)3)2)2C₆H₄CN

Chemical Property of ZnN₄C₂₀H₉(C₆H₃(C(CH₃)3)2)2C₆H₄CN

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ZnN₄C₂₀H₉(C₆H₃(C(CH₃)3)2)2C₆H₄CN

There total 1 articles about ZnN₄C₂₀H₉(C₆H₃(C(CH₃)3)2)2C₆H₄CN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

[5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II) (220355-76-0) + 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile (214360-46-0) → ZnN4C20H9(C6H3(C(CH3)3)2)2C6H4CN (637765-01-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In toluene; ZnN4C20H9I(C(CH3)3)2, C6H4(CN)BO2C2(CH3)4, Suzuki coupling, Cs2CO3, Pd(P(C6H5)3)4, toluene, reflux, 18 h;

DOI:10.1002/anie.200352265

Reference yield: 89.0%

ZnN4C20H9(C6H3(C(CH3)3)2)2C6H4CN (637765-01-6) → μ-[10,10'-bis(3-cyanophenyl)-5,5',15,15'-tetrakis[3,5-di(tert-butyl)phenyl]-18,18':20,20'-dicyclo-2,2'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II) (637765-00-5)

Guidance literature:

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; scandium tris(trifluoromethanesulfonate); In toluene; 2,3-dichloro-5,6-dicyano-1,4-benzoquinone, Sc(OSO2CF3)3, toluene, reflux, 30 min;

DOI:10.1002/anie.200352265

Reference yield: 80.0%

ZnN4C20H9(C6H3(C(CH3)3)2)2C6H4CN (637765-01-6) → [ZnN4C20H8(C6H3(C(CH3)3)2)2C6H4CN]2 (637765-04-9)

Guidance literature:

With silver(I) hexafluorophosphate; In chloroform; acetonitrile; AgPF6, CH3CN/CHCl3 1:6, room temp., 15 h;

DOI:10.1002/anie.200352265

upstream raw materials:

[5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile

Downstream raw materials:

[ZnN₄C₂₀H₈(C₆H₃(C(CH₃)3)2)2C₆H₄CN]2

μ-[10,10'-bis(3-cyanophenyl)-5,5',15,15'-tetrakis[3,5-di(tert-butyl)phenyl]-18,18':20,20'-dicyclo-2,2'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

Refernces