[5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

Base Information

Chemical Name:[5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)
CAS No.:220355-76-0
Molecular Formula:C₄₈H₅₁IN₄Zn
Molecular Weight:876.254
Hs Code.:

Synonyms:[5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

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Chemical Property of [5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

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Technology Process of [5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

There total 2 articles about [5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 187387-14-0
[5,15-bis-(3,5-di-tert-butylphenyl)porphyrinato]zinc(II)

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 220355-76-0
[5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

Guidance literature:: With silver(I) hexafluorophosphate; In pyridine; chloroform; AgPF6, I2, pyridine/CHCl3 1:60, room temp.;
DOI:10.1002/anie.200352265

Reference yield: 63.0%

: [5,15-bis[3,5-di(tert-butyl)phenyl]porphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 220355-76-0
[5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

: 866321-86-0
[5,15-bis[3,5-di(tert-butyl)phenyl]-1,10-diiodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

Guidance literature:: With AgPF₆; In pyridine; chloroform; acetonitrile; N2 atm.; a soln. of AgPF6 in CH3CN was added at 25°C to a soln. of complex and I2 in CHCl3/pyridine 30:1, 13 min; H2O was added, the organic layer was washed with H2O, dried (Na2SO4), evapd. in vac., flash chromy. (silica gel; cyclohexane/CH2Cl2 1:1. 1% v/v (C2H5)3N);
DOI:10.1002/hlca.200590144

Reference yield: 67.0%

: 220355-76-0
[5,15-bis[3,5-di(tert-butyl)phenyl]-10-iodoporphyrinato(2-)-κN(21),κN(22),κN(23),κN(24)]zinc(II)

: 214360-46-0
3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile

: 637765-01-6
ZnN₄C₂₀H₉(C₆H₃(C(CH₃)3)2)2C₆H₄CN

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In toluene; ZnN4C20H9I(C(CH3)3)2, C6H4(CN)BO2C2(CH3)4, Suzuki coupling, Cs2CO3, Pd(P(C6H5)3)4, toluene, reflux, 18 h;
DOI:10.1002/anie.200352265