N-methyl-N-nitroso-carbamate de p-nitrophenyle

Base Information

• Chemical Name: N-methyl-N-nitroso-carbamate de p-nitrophenyle
• CAS No.: 75744-83-1
• Molecular Formula: C₈H₇N₃O₅
• Molecular Weight: 225.161
• Mol file: 75744-83-1.mol

Synonyms:N-methyl-N-nitroso-carbamate de p-nitrophenyle

Chemical Property of N-methyl-N-nitroso-carbamate de p-nitrophenyle

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-methyl-N-nitroso-carbamate de p-nitrophenyle

There total 2 articles about N-methyl-N-nitroso-carbamate de p-nitrophenyle which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4-nitrophenyl N-methylcarbamate (5819-21-6) → N-methyl-N-nitroso-carbamate de p-nitrophenyle (75744-83-1)

Guidance literature:

With pyridine; nitrosylchloride;

Reference yield:

4-Nitrophenyl chloroformate (7693-46-1) → N-methyl-N-nitroso-carbamate de p-nitrophenyle (75744-83-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 1,4-dioxane / 12 h / Reflux; Inert atmosphere

2: sodium acetate; dinitrogen tetraoxide / dichloromethane / 1 h / -40 °C

With sodium acetate; dinitrogen tetraoxide; In 1,4-dioxane; dichloromethane;

DOI:10.1016/j.ejmech.2014.05.032

Reference yield: 40.0%

2-(2-aminoethoxy)ethyl-9-hydroxy-6-methylellipticinium chloride (1618136-76-7) + N-methyl-N-nitroso-carbamate de p-nitrophenyle (75744-83-1) → C24H28N5O4(1+)*Cl(1-) (1618136-86-9)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide; at 0 ℃; for 7h;

DOI:10.1016/j.ejmech.2014.05.032

upstream raw materials:

4-nitrophenyl N-methylcarbamate

4-Nitrophenyl chloroformate

Downstream raw materials:

C₂₄H₂₈N₅O₄⁽¹⁺⁾*Cl^(1-)

C₂₅H₃₀N₅O₃⁽¹⁺⁾*Cl^(1-)