2,2'-Ethylenebis(6-hydroxymethyl)-4-benzoquinone

Base Information

Chemical Name:2,2'-Ethylenebis(6-hydroxymethyl)-4-benzoquinone
CAS No.:87050-82-6
Molecular Formula:C20H18O8
Molecular Weight:386.35212
Hs Code.:
Mol file:87050-82-6.mol

Synonyms:2,2'-ethylenebis[6-(hydroxymethyl)-p-benzoquinone] diacetate;2,2'-Ethylenebis(6-hydroxymethyl)-4-benzoquinone;ethane-1,2-diylbis[(2,5-dioxocyclohexa-3,6-diene-3,1-diyl)methanediyl] diacetate;2,2'-Ebhmb;

Suppliers and Price of 2,2'-Ethylenebis(6-hydroxymethyl)-4-benzoquinone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 2,2'-Ethylenebis(6-hydroxymethyl)-4-benzoquinone

Chemical Property:

Vapor Pressure:2.98E-11mmHg at 25°C
Boiling Point:528.4°C at 760 mmHg
Flash Point:231.1°C
PSA：120.88000
Density:1.319g/cm³
LogP:0.90200

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2,2'-Ethylenebis(6-hydroxymethyl)-4-benzoquinone

There total 9 articles about 2,2'-Ethylenebis(6-hydroxymethyl)-4-benzoquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 87050-78-0
1,2-bis<3-<(acetyloxy)methyl>-2,5-dimethoxyphenyl>ethane

: 87050-82-6
2,2'-ethylenebis[6-(hydroxymethyl)-p-benzoquinone] diacetate

Guidance literature:: With ammonium cerium(IV) nitrate; In water; acetonitrile; for 0.5h; Ambient temperature;
DOI:10.1021/jm00366a004

Reference yield:

: 21893-97-0
2,6-bis(hydroxymethyl)-4-methoxyphenol

: 87050-82-6
2,2'-ethylenebis[6-(hydroxymethyl)-p-benzoquinone] diacetate

Guidance literature:: Multi-step reaction with 7 steps

1: 90 percent / K₂CO₃ / acetone / 48 h / Heating

2: 62 percent / pyridinium chlorochromate / acetone / 2.5 h / Ambient temperature

3: 100 percent / pyridine / Ambient temperature

4: 1.) NaH / 1.) benzene, reflux, 2 h, 2.) benzene, reflux, overnight

5: 56 percent / pyridine / Ambient temperature

6: 100 percent / CoCl₂, NaBH₄ / tetrahydrofuran; ethanol / 1.) 0 deg C, 10 min, 2.) RT, overnight

7: 99 percent / ceric ammonium nitrate / H₂O; acetonitrile / 0.5 h / Ambient temperature

With pyridine; sodium tetrahydroborate; ammonium cerium(IV) nitrate; sodium hydride; potassium carbonate; pyridinium chlorochromate; In tetrahydrofuran; ethanol; water; acetone; acetonitrile;
DOI:10.1021/jm00366a004

Reference yield:

: 78840-04-7
[3-(hydroxymethyl)-2,5-dimethoxyphenyl]methanol

: 87050-82-6
2,2'-ethylenebis[6-(hydroxymethyl)-p-benzoquinone] diacetate

Guidance literature:: Multi-step reaction with 6 steps

1: 62 percent / pyridinium chlorochromate / acetone / 2.5 h / Ambient temperature

2: 100 percent / pyridine / Ambient temperature

3: 1.) NaH / 1.) benzene, reflux, 2 h, 2.) benzene, reflux, overnight

4: 56 percent / pyridine / Ambient temperature

5: 100 percent / CoCl₂, NaBH₄ / tetrahydrofuran; ethanol / 1.) 0 deg C, 10 min, 2.) RT, overnight

6: 99 percent / ceric ammonium nitrate / H₂O; acetonitrile / 0.5 h / Ambient temperature

With pyridine; sodium tetrahydroborate; ammonium cerium(IV) nitrate; sodium hydride; pyridinium chlorochromate; In tetrahydrofuran; ethanol; water; acetone; acetonitrile;
DOI:10.1021/jm00366a004