Methanol, 4-biphenyldiphenyl-

Base Information

• Chemical Name: Methanol, 4-biphenyldiphenyl-
• CAS No.: 38696-14-9
• Molecular Formula: C25H20O
• Molecular Weight: 336.433
• Hs Code.: 2906299090
• European Community (EC) Number: 653-121-1
• NSC Number: 28085
• DSSTox Substance ID: DTXSID20959521
• Nikkaji Number: J668.388F
• Wikidata: Q82940306
• Mol file: 38696-14-9.mol

Synonyms:38696-14-9;Methanol, 4-biphenyldiphenyl-;NSC28085;4-Biphenyldiphenylmethanol;SCHEMBL813153;DTXSID20959521;[1, .alpha.,.alpha.-diphenyl-;NSC-28085;AKOS024333372;[1,1'-Biphenyl]-4-yldiphenylmethanol;([1,1'-Biphenyl]-4-yl)(diphenyl)methanol;ALPHA,ALPHA-DIPHENYL-4-BIPHENYLMETHANOL

Chemical Property of Methanol, 4-biphenyldiphenyl-

Chemical Property:

• Vapor Pressure: 3.12E-11mmHg at 25°C
• Boiling Point: 510.2°C at 760 mmHg
• Flash Point: 191.8°C
• PSA: 20.23000
• Density: 1.138g/cm³
• LogP: 5.63780
• XLogP3: 5.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 336.151415257
• Heavy Atom Count: 26
• Complexity: 386

Purity/Quality:

99%min ^*data from raw suppliers

ALPHA,ALPHA-DIPHENYL-4-BIPHENYLMETHANOL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC=C(C=C2)C(C3=CC=CC=C3)(C4=CC=CC=C4)O

Technology Process of Methanol, 4-biphenyldiphenyl-

There total 16 articles about Methanol, 4-biphenyldiphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

biphenyl-4-yl-phenyl-methanone (2128-93-0) + phenylmagnesium bromide → 4-biphenylyldiphenylmethanol (38696-14-9)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 2h;

DOI:10.1081/SCC-120028367

Reference yield: 73.7%

thianthrene cation radical perchlorate (35787-71-4) + triphenyl(phenylazo)methane (981-18-0) → triphenylmethyl alcohol (76-84-6) + thianthrene-5-oxide (2362-50-7) + 4-biphenylyldiphenylmethanol (38696-14-9) + 5-phenylthianthreniumyl perchlorate (65886-50-2)

Guidance literature:

In acetonitrile; Further byproducts given; Ambient temperature;

Reference yield: 73.0%

biphenyl-4-yl-phenyl-methanone (2128-93-0) + phenylmagnesium bromide (100-58-3) → 4-biphenylyldiphenylmethanol (38696-14-9)

Guidance literature:

In diethyl ether; at 20 ℃; for 3h; Inert atmosphere; Reflux;

DOI:10.1039/c5ce00871a

upstream raw materials:

benzophenone

4'-biphenyl chloride

biphenyl-2-yl-lithium

methyl 4-phenylbenzoate

Downstream raw materials:

5-(biphenyl-4-yl-diphenyl-methyl)-pyridin-2-ol

Biphenyl-4-yl(diphenyl)methyl chloride

1-(biphenyl-4-yl-diphenyl-methoxy)-propan-2-ol

2-[1,1-diphenyl-4-(phenyl)phenylmethylthio]ethanamine

Refernces

• 1、 Knepper, Ingo,Seichter, Wilhelm,Skobridis, Konstantinos,Theodorou, Vassiliki,Weber, Edwin. "Aspects of crystal engineering arising from packing behavior of functional mono para-substituted trityl compounds". . p. 6355 - 6369. Retrieved 2015/08/24.
• 2、 Saito, Shinichi,Ohwada, Tomohiko,Shudo, Koichi. "Superacid-catalyzed reaction of substituted benzaldehydes with benzene". . p. 8089 - 8093. Retrieved 2007/10/03.