methyl 3,5-bis(methoxymethoxy)-4-<2-(methoxymethoxy)-6-(1,3-dioxanyl)benzoyl>benzoate

Base Information

Chemical Name:methyl 3,5-bis(methoxymethoxy)-4-<2-(methoxymethoxy)-6-(1,3-dioxanyl)benzoyl>benzoate
CAS No.:159425-47-5
Molecular Formula:C₂₅H₃₀O₁₁
Molecular Weight:506.507
Hs Code.:

Synonyms:methyl 3,5-bis(methoxymethoxy)-4-<2-(methoxymethoxy)-6-(1,3-dioxanyl)benzoyl>benzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 3,5-bis(methoxymethoxy)-4-<2-(methoxymethoxy)-6-(1,3-dioxanyl)benzoyl>benzoate

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Technology Process of methyl 3,5-bis(methoxymethoxy)-4-<2-(methoxymethoxy)-6-(1,3-dioxanyl)benzoyl>benzoate

There total 12 articles about methyl 3,5-bis(methoxymethoxy)-4-<2-(methoxymethoxy)-6-(1,3-dioxanyl)benzoyl>benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 67-56-1
methanol

: 159425-45-3
3,5-bis(methoxymethoxy)-4-<2-(methoxymethoxy)-6-(1,3-dioxanyl)benzoyl>benzaldehyde

: 159425-47-5
methyl 3,5-bis(methoxymethoxy)-4-<2-(methoxymethoxy)-6-(1,3-dioxanyl)benzoyl>benzoate

Guidance literature:: With potassium hydroxide; iodine; 1.) 0 deg C, 3 h, 2.) r.t., 1 h;
DOI:10.1021/jo00101a032

Reference yield:

: 100-83-4
meta-hydroxybenzaldehyde

: 159425-47-5
methyl 3,5-bis(methoxymethoxy)-4-<2-(methoxymethoxy)-6-(1,3-dioxanyl)benzoyl>benzoate

Guidance literature:: Multi-step reaction with 8 steps

1: 81 percent / Al₂O₃ / toluene / Heating

2: 96 percent / NaH / tetrahydrofuran; dimethylformamide

3: n-BuLi / cyclohexane; hexane / 1.) r.t., 15 min, 2.) r.t., 15 min

4: n-BuLi / tetrahydrofuran / Ambient temperature

5: 100 percent / MnO₂ / CH₂Cl₂ / 16 h / Ambient temperature

6: 93 percent / TBAF / tetrahydrofuran / 1 h / Ambient temperature

7: 84 percent / MnO₂ / CH₂Cl₂ / 48 h

8: 90 percent / KOH, I₂ / 1.) 0 deg C, 3 h, 2.) r.t., 1 h

With manganese(IV) oxide; potassium hydroxide; n-butyllithium; tetrabutyl ammonium fluoride; iodine; sodium hydride; aluminum oxide; In tetrahydrofuran; hexane; dichloromethane; cyclohexane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jo00101a032

Reference yield:

: 2150-44-9
1-carbomethoxy-3,5-dihydroxybenzene

: 159425-47-5
methyl 3,5-bis(methoxymethoxy)-4-<2-(methoxymethoxy)-6-(1,3-dioxanyl)benzoyl>benzoate

Guidance literature:: Multi-step reaction with 8 steps

1: 75 percent / diisopropylethylamine / CH₂Cl₂ / Ambient temperature

2: 100 percent / LiAlH₄ / tetrahydrofuran / 2 h / Ambient temperature

3: 87 percent / imidazole / CH₂Cl₂

4: n-BuLi / tetrahydrofuran / Ambient temperature

5: 100 percent / MnO₂ / CH₂Cl₂ / 16 h / Ambient temperature

6: 93 percent / TBAF / tetrahydrofuran / 1 h / Ambient temperature

7: 84 percent / MnO₂ / CH₂Cl₂ / 48 h

8: 90 percent / KOH, I₂ / 1.) 0 deg C, 3 h, 2.) r.t., 1 h

With 1H-imidazole; manganese(IV) oxide; potassium hydroxide; lithium aluminium tetrahydride; n-butyllithium; tetrabutyl ammonium fluoride; iodine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo00101a032