tert-butyl (2E)-3-(3-chlorophenyl)prop-2-enoate

Base Information

Chemical Name:tert-butyl (2E)-3-(3-chlorophenyl)prop-2-enoate
CAS No.:309757-75-3
Molecular Formula:C₁₃H₁₅ClO₂
Molecular Weight:238.714
Hs Code.:
DSSTox Substance ID:DTXSID501208573
Nikkaji Number:J1.363.521H,J3.092.169K

Synonyms:309757-75-3;DTXSID501208573;EN300-844687;tert-butyl (2E)-3-(3-chlorophenyl)prop-2-enoate;1,1-Dimethylethyl (2E)-3-(3-chlorophenyl)-2-propenoate

Suppliers and Price of tert-butyl (2E)-3-(3-chlorophenyl)prop-2-enoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of tert-butyl (2E)-3-(3-chlorophenyl)prop-2-enoate

Chemical Property:

XLogP3:3.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:238.0760574
Heavy Atom Count:16
Complexity:266

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)OC(=O)C=CC1=CC(=CC=C1)Cl
Isomeric SMILES:CC(C)(C)OC(=O)/C=C/C1=CC(=CC=C1)Cl

Technology Process of tert-butyl (2E)-3-(3-chlorophenyl)prop-2-enoate

There total 5 articles about tert-butyl (2E)-3-(3-chlorophenyl)prop-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 24424-99-5
di-tert-butyl dicarbonate

: 1866-38-2,14473-90-6
m-Chlorocinnamic acid

: 309757-75-3
tert-butyl (E)-3-(3-chlorophenyl)prop-2-enoate

Guidance literature:: With dmap; In tetrahydrofuran; at 20 ℃; for 14h;
DOI:10.1021/jm010100v

Reference yield: 92.0%

: 1663-39-4,25232-27-3
tert-Butyl acrylate

: 456-39-3
3-chlorobenzenediazonium tetrafluoroborate

: 309757-75-3
tert-butyl (E)-3-(3-chlorophenyl)prop-2-enoate

Guidance literature:: With 3-benzyl-1-(2-hydroxy-2-phenylethyl)imidazolium chloride; palladium diacetate; In ethanol; at 36 ℃; for 3h;
DOI:10.1002/ejoc.201200181

Reference yield: 92.0%

: 27784-76-5
tert-butyl diethylphosphonoacetate

: 587-04-2
m-Chlorobenzaldehyde

: 309757-75-3
tert-butyl (E)-3-(3-chlorophenyl)prop-2-enoate

Guidance literature:: tert-butyl diethylphosphonoacetate; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h;

m-Chlorobenzaldehyde; In tetrahydrofuran; at -78 - 20 ℃; for 2h; Further stages.;
DOI:10.1039/b108573p