trans-{PtCOPh(Cl)(PPh₃)2}

Base Information

Chemical Name:trans-{PtCOPh(Cl)(PPh₃)2}
CAS No.:18421-48-2
Molecular Formula:C₄₃H₃₅ClOP₂Pt
Molecular Weight:860.231
Hs Code.:

Synonyms:trans-{PtCOPh(Cl)(PPh₃)2}

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Chemical Property of trans-{PtCOPh(Cl)(PPh₃)2}

Chemical Property:

Purity/Quality:

Safty Information:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of trans-{PtCOPh(Cl)(PPh₃)2}

There total 11 articles about trans-{PtCOPh(Cl)(PPh₃)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 10199-34-5,14056-88-3,15604-36-1
cis-dichlorobis(triphenylphosphine)platinum(II)

: 98-88-4
benzoyl chloride

: 18421-48-2
trans-{PtCOPh(Cl)(PPh₃)2}

Guidance literature:: In acetonitrile; benzene; Electrolysis; a MeCN-benzene soln. of Pt-complex was electrolyzed at -1.60 V vs. Ag/AgCl under Ar to zero current (Hg working electrode, Pt wire counterelectrode, n-Bu4ClO4, suspended activated Al2O3, two-electron reduction), filtered, PhCOCl was added; evapd., residue was extd. with benzene, ext. filtered, concd., examined by (31)P NMR spectroscopy (NMR yield is given);
DOI:10.1021/om00137a038

Reference yield:

: 12120-15-9
ethylenebis(triphenylphosphine)platinum⁽⁰⁾

: 98-88-4
benzoyl chloride

: 18421-48-2
trans-{PtCOPh(Cl)(PPh₃)2}

: 618-32-6
Benzoyl bromide

Guidance literature:: In benzene-d6; at 35 ℃; Equilibrium constant; Glovebox;
DOI:10.1021/om400157a

Reference yield:

: trans-platinum(triphenylphosphine)2(COCOPh) chloride

: 18421-48-2
trans-{PtCOPh(Cl)(PPh₃)2}

Guidance literature:: In toluene; byproducts: CO; 70.0, 80.0, 90.0°C, PPh3 added in some cases; not isolated, monitored by 31P-NMR, IR, UV; Kinetics;
DOI:10.1021/ja00235a023