NMo(N[((t)Bu)(3,5-C₆H₃Me₂)])3

Base Information

• Chemical Name: NMo(N[((t)Bu)(3,5-C₆H₃Me₂)])3
• CAS No.: 256240-25-2
• Molecular Formula: C₃₆H₅₄MoN₄
• Molecular Weight: 638.792

Synonyms:NMo(N[((t)Bu)(3,5-C₆H₃Me₂)])3

Chemical Property of NMo(N[((t)Bu)(3,5-C₆H₃Me₂)])3

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Technology Process of NMo(N[((t)Bu)(3,5-C₆H₃Me₂)])3

There total 14 articles about NMo(N[((t)Bu)(3,5-C₆H₃Me₂)])3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

Mo(N[((t)Bu)(3,5-C6H3Me2)])3 + nitrogen (7727-37-9) → NMo(N[((t)Bu)(3,5-C6H3Me2)])3 (256240-25-2)

Guidance literature:

With NaH; In tetrahydrofuran; stirring soln. of molybdenum compd. in THF in presence of purified NaH under N2;

DOI:10.1021/ja066090a

Reference yield: 80.0%

(3,5-Me2C6H3)[neopentyl]N)3Nb(μ-N2)Mo(N[t-butyl]-3,5-Me2C6H3)3 → NMo(N[((t)Bu)(3,5-C6H3Me2)])3 (256240-25-2) + [Na][NNb(N[neopentyl]-3,5-Me2C6H3)3]

Guidance literature:

With sodium amalgam; In tetrahydrofuran; under N2 atm. to soln. Mo-Nb complex in THF was added Na-Hg, mixt. was allowed to stir at room temp. for 2 h; soln. was decanted from Na-Hg, evapd., residue was extracted with pentane, filrtered through Celite, evapd., residue was dissolved in pentane, stored to -35°C, filtrate was evapd., residue was dissolved in Et2O, stored -35°C;

DOI:10.1021/ja056408j

Reference yield: 72.83%

Mo(N[((t)Bu)(3,5-C6H3Me2)])3 + 2,4,6-trimethylaniline azide (14213-00-4) → NMo(N[((t)Bu)(3,5-C6H3Me2)])3 (256240-25-2)

Guidance literature:

In diethyl ether; (N2 or Ar); mixing at -35°C, stirring (29°C, 3 h ), removal of ether; recryctn. (-35°C, ether); elem. anal.;

DOI:10.1021/ja960574x

upstream raw materials:

nitrogen

2,4,6-trimethylaniline azide

(3,5-Me2C6H3(t-Bu)N)3Mo(III)-(μ-N2)-Mo(III)(N(t-Bu)C6H3Me2-3,5)3

[Mo(N[t-Bu][3,5-C6H3Me2])3]2(μ-NCPhCPhN)

Downstream raw materials:

[MeCONMo(N(tert-Bu)C₆H₃(CH₃)2)3](OTf)

[tert-BuCONMo(N(tert-Bu)C₆H₃(CH₃)2)3](OTf)

[Mo(N((t)Bu)(C₆H₃-3,5-Me₂))3NC(O)Ph]O₃SCF₃

[Mo(N((t)Bu)(C₆H₃-3,5-Me₂))3NMe]I

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