3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-aldehydo-D-glycero-D-ido-heptose

Base Information

Chemical Name:3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-aldehydo-D-glycero-D-ido-heptose
CAS No.:652993-93-6
Molecular Formula:C₃₀H₃₃NO₆
Molecular Weight:503.595
Hs Code.:

Synonyms:3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-aldehydo-D-glycero-D-ido-heptose

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Chemical Property of 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-aldehydo-D-glycero-D-ido-heptose

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Technology Process of 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-aldehydo-D-glycero-D-ido-heptose

There total 4 articles about 3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-aldehydo-D-glycero-D-ido-heptose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 537031-63-3
(E)-1-(2'-N-acetylamino-3',4',6'-tri-O-benzyl-2'-deoxy-α-D-glucopyranosyl)-2-propene

: 652993-93-6
3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-aldehydo-D-glycero-D-ido-heptose

Guidance literature:: With sodium periodate; osmium(VIII) oxide; In tetrahydrofuran; water; tert-butyl alcohol; at 20 ℃; for 20h;
DOI:10.1081/CAR-120026465

Reference yield:

: 180778-36-3
3-(2'-acetamido-3',4',6-tri-O-acetyl-2'-deoxy-α-D-glucopyranosyl)-1-propene

: 652993-93-6
3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-aldehydo-D-glycero-D-ido-heptose

Guidance literature:: Multi-step reaction with 4 steps

1: NaOMe; MeOH

2: NaH / dimethylformamide / 20 °C

3: 87 percent / (Ph₂Me)2IrCOD*PF₆ / tetrahydrofuran / 2 h / 20 °C

4: O₃; Ph₃P / CH₂Cl₂

With methanol; (Ph₂Me)2IrCOD*PF₆; sodium methylate; sodium hydride; ozone; triphenylphosphine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(03)00818-9

Reference yield:

: 214193-76-7
1-(2'-acetamido-2'-deoxy-α-D-glucopyranosyl)-2-propene

: 652993-93-6
3-acetamido-2,6-anhydro-4,5,7-tri-O-benzyl-3-deoxy-aldehydo-D-glycero-D-ido-heptose

Guidance literature:: Multi-step reaction with 3 steps

1: NaH / dimethylformamide / 20 °C

2: 87 percent / (Ph₂Me)2IrCOD*PF₆ / tetrahydrofuran / 2 h / 20 °C

3: O₃; Ph₃P / CH₂Cl₂

With (Ph₂Me)2IrCOD*PF₆; sodium hydride; ozone; triphenylphosphine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(03)00818-9